CAS 7688-51-9 N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine (HCID 82125)

名称と識別子

優先名称: N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
IUPAC: N,N-bis(trimethylsilyl)prop-2-en-1-amine
現地名: N,N-ビス(トリメチルシリル)-2-プロペン-1-アミン
英語名: N-Allyl-n N-bis(trimethylsilyl)amine
分子式: C9H23NSi2
分子量: 201.46

名称と別名

7688-51-9N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamineEINECS 231-699-2DTXSID50227684Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-RefChem:828934DTXCID00150175231-699-2N,N-Bis(trimethylsilyl)allylamineN-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINEN,N-bis(trimethylsilyl)prop-2-en-1-amineN-Allyl-N,N-bis(trimethylsilyl)amine

名称をさらに表示

α,α,α-トリメチル-N-(2-プロペニル)-N-(トリメチルシリル)シランアミンN,N-ビス(トリメチルシリル)-2-プロペン-1-アミンN,N-ビス(トリメチルシリル)アリルアミンアリルビス(トリメチルシリル)アミンN-アリル-N,N-ビス(トリメチルシリル)アミン1,1,1,3,3,3-ヘキサメチル-2-アリルプロパンジシラザン(プロパ-2-エン-1-イル)ビス(トリメチルシリル)アミンDitrimethylsilyl allylamineN,N'-bis(trimethylsilyl)allylamineProp-2-en-1-ylbis(trimethylsilyl)amineN-Allyl-N,N-bis(trimethylsilyl)amine 97%2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&

3-Bis(trimethylsilyl)amino-1-propene(prop-2-en-1-yl)bis(trimethylsilyl)amineMFCD00545193N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamineC9H23NSi2Allylbis(trimethylsilyl)amine578932_ALDRICH, EINECS 231-699-2, MolPort-003-937-319, N,N-Bis(trimethylsilyl)allylamine, CID82125, N-Allyl-N,N-bis(trimethylsilyl)amine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine, Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-, 7688-51-9AHL726ZXM9

データベース識別子

CAS: 7688-51-9
PubChem CID: 82125
DTXSID: DTXSID50227684
UNII: AHL726ZXM9
EC Number: 231-699-2
Nikkaji: J125.864H

物性

構造計算による物性

極性表面積: 3.2 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 4
重原子数: 12
形式電荷: 0
複雑度: 139

物理化学的性質

沸点: 72 °C/15 · 72 °C/15 mmHg (lit.)
比重(密度): 0.816 g/mL · 0.816 g/mL at 25 °C (lit.)
屈折率: 20 · n20/D 1.440(lit.)
闪点: 109 °F · 109 °F
外見: 液体
比重: 0.817 · 0.817
InChI: 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
InChIKey: CVNCFZIIZGNVFD-UHFFFAOYSA-N
SMILES: C[Si](C)(C)N(CC=C)[Si](C)(C)C

安全と法規制

GHS分類

GHS Classification · 5 件

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 2 件

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesFlam. Liq. 3 (100%)；Skin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (100%)

法規制情報

Regulatory Information · 2 件

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

安全データ

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
risk_code: 10-36/37/38
hazard_code: Xi
safety_code: 16-26-36/37
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing InformationSilanamine, 1,1,1-trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)-: ACTIVE

応用分野 · 1 件

使用N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare: Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions. Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride. Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.