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ペンタフルオロひ素(V)

Arsenic pentafluoride

HCID 82223
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
7784-36-3
標準SMILES
F[As](F)(F)(F)F
InChIKey
YBGKQGSCGDNZIB-UHFFFAOYSA-N
分子式
AsF5
平均分子量
169.9136 g/mol
単同位体質量
169.91361

概要

Arsenic pentafluoride is a pnictogen halide.

名称と識別子

優先名称
Arsenic pentafluoride
IUPAC
pentafluoro-λ5-arsane
現地名
ペンタフルオロひ素(V)
英語名
ARSENIC PENTAFLUORIDE
分子式
AsF5
分子量
169.91

名称と別名

Arsenic pentafluoridePentafluoroarsorane7784-36-3Arsorane, pentafluoro-AsF5pentafluoro-lambda5-arsanepentafluoridoarsenicI54752Q0OJpentafluoro-lambda(5)-arsaneDTXSID4064842CHEBI:30530(AsF5)
名称をさらに表示
ひ素(V)フルオリドペンタフルオロひ素(V)ペンタフルオロアルソランひ素(V)ペンタフルオリド五ふっ化ひ素ペンタフルオロアルシンふっ化ひ素(V)ペンタフルオロ-λ5-アルサンArsenicfluoride2Einecs 232-061-6PentafluoroarsineARSENIC (V) FLUORIDEArsenic pentfluorideFive fluoride arsenicArsenic(V)pentafluoride
[AsF5]RefChem:114185DTXCID1048045232-061-6arsenic(V) fluorideArsenic fluoride (AsF5)UNII-I54752Q0OJarsenic(V)fluoride

データベース識別子

CAS
7784-36-3
PubChem CID
82223
DTXSID
DTXSID4064842
ChEBI
CHEBI:30530
UNII
I54752Q0OJ
EC Number
232-061-6
Nikkaji
J95.336I

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
5
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
37.1

実験および物理化学的性質

Chemical Classes · 2 件

Metals -> Arsenic Compounds, Inorganic

Carcinogens

Physical DescriptionColorless gas; Makes white clouds in moist air; Hydrolyzed instantly by water; [Merck Index]

物理化学的性質

融点
-79 · -79,8°C
沸点
-52 · -52,8°C
比重(密度)
25.8 · dliq25.8 2.33
溶解性
2 O; · reacts with H2O; soluble in ethanol,benzene, ethyl ether
外見
無色のガス
色
colorless
水溶解度
6 · 水中で急速に加水分解される;可溶性アルコール、ベンゼン、エーテル [MER06]
CAS データベース
7784 · 7784-36-3
EPAの化学物質情報
Arsenic pentafluoride (7784-36-3)
化学的性質 · 1 件

化学的特性colorless gas; condenses to yellow liquid; forms white clouds in moist air; enthalpy of vaporization 20.8 kJ/mol; dielectric constant, 12.8 (20°C); can be formed by reacting AsF3 with fluorine; used as a doping agent for electroconductive polymers [HAW93] [KIR78] [MER06] [CRC10]

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H280 (100%): Contains gas under pressure; may explode if heated [Warning Gases under pressure]

P260, P271, P273, P284, P304+P340, P316, P320, P391, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 111 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H280: Contains gas under pressure; may explode if heated [Warning Gases under pressure]

危険有害性情報

Regulatory Information · 2 件

Restricted substance: Pentafluoroarsorane

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Hazards SummarySee Arsenic and the linked occupational diseases.
Hazard Classes and Categories · 4 件

Press. Gas (Liq.) (100%)

Gases under pressure - Compressed gas or Liquefied gas

Gases under pressure - Compressed gas or Liquefied gas

Carcinogens, Reactive agents - 1st degree

安全と保護具

Exposure Control and Personal Protection · 2 件

Biological Exposure Indices (BEI) [ACGIH] - Inorganic arsenic plus methylated metabolites in urine = 35 ug As/L; end of workweek; Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Minimum Risk Level

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Arsenic is absorbed mainly by inhalation or ingestion, as to a lesser extent, dermal exposure. It is then distributed throughout the body, where it is reduced into arsenite if necessary, then methylated into monomethylarsenic (MMA) and dimethylarsenic acid (DMA) by arsenite methyltransferase. Arsenic and its metabolites are primarily excreted in the urine. Arsenic is known to induce the metal-binding protein metallothionein, which decreases the toxic effects of arsenic and other metals by binding them and making them biologically inactive, as well as acting as an antioxidant. (L20)

用途と製造

Uses · 2 件

Used in electroconductive polymers as a doping agent; [Hawley]

Semiconductor Manufacturing [Category: Industry]

General Manufacturing InformationArsorane, pentafluoro-: ACTIVE

応用分野

使用Doping agent in electroconductive polymers.

サプライヤー10 社

安徽旺山旺水特种气体有限公司15906197626 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
尚澜气体(上海)有限公司4001882517 13194677939 · [email protected]
上海嘉斯保气体有限公司13218776790 13218776790 · [email protected]
南兴化工(江苏)有限公司0512-66387035 18662433356 · [email protected]

関連反応

0 件
反応記録を作成

現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
Acute Oral: 0.005 mg/kg/day (L134) Chronic Oral: 0.0003 mg/kg/day (L134) Chronic Inhalation: 0.01 mg/m3 (L134)
Threshold Limit Values (TLV)0.01 [mg/m3], as As (2.5 mg/m3, as F)
Permissible Exposure Limit (PEL)0.01 [mg/m3], as As (2.5 mg/m3, as F)
Immediately Dangerous to Life or Health (IDLH)5.0 [mg/m3], as As

毒性情報

Treatment · 1 件

Arsenic poisoning can be treated by chelation therapy, using chelating agents such as dimercaprol, EDTA or DMSA. Charcoal tablets may also be used for less severe cases. In addition, maintaining a diet high in sulfur helps eliminate arsenic from the body. (L20)

Health EffectsArsenic poisoning can lead to death from multi-system organ failure, probably from necrotic cell death, not apoptosis. Arsenic is also a known carcinogen, esepcially in skin, liver, bladder and lung cancers. (T1, L20)
Adverse EffectsNeurotoxin - Sensorimotor
Exposure RoutesOral (L2) ; inhalation (L2) ; dermal (L2)
Toxicity Summary · 1 件

Arsenic and its metabolites disrupt ATP production through several mechanisms. At the level of the citric acid cycle, arsenic inhibits pyruvate dehydrogenase and by competing with phosphate it uncouples oxidative phosphorylation, thus inhibiting energy-linked reduction of NAD+, mitochondrial respiration, and ATP synthesis. Hydrogen peroxide production is also increased, which might form reactive oxygen species and oxidative stress. Arsenic's carginogenicity is influenced by the arsenical binding of tubulin, which results in aneuploidy, polyploidy and mitotic arrests. The binding of other arsenic protein targets may also cause altered DNA repair enzyme activity, altered DNA methylation patterns and cell proliferation. (T1, A17)

Signs and SymptomsExposure to lower levels of arsenic can cause nausea and vomiting, decreased production of red and white blood cells, abnormal heart rhythm, damage to blood vessels, and a sensation of
Carcinogen Classification1, carcinogenic to humans. (L135)

安全データ

tsca
TSCA listed
ridadr
3162
risk_code
23/25
hazard_code
T
hazard_note
Toxic
safety_code
20/21-28-45
hazard_class
2.3
上海万千化工有限公司18796480002 18796480002 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
湖北玖天生物医药科技有限公司027-88013699 17354350817 · [email protected]
上海亿万化工有限公司00-18662433356 18662433356 · [email protected]

補足説明

定義Readily hydrolyzed, soluble in alcohol and benzene.