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臭化鉄(II)無水

Ferrous bromide

HCID 82240
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
7789-46-0
標準SMILES
[Br-].[Br-].[Fe+2]
InChIKey
GYCHYNMREWYSKH-UHFFFAOYSA-L
分子式
Br2Fe
平均分子量
215.65 g/mol
単同位体質量
213.77161

概要

Iron(II) bromide is a chemical compound of iron and bromine. It is useful synthetic intermediate. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L653)

名称と識別子

優先名称
Ferrous bromide
IUPAC
iron(2+) dibromide
現地名
臭化鉄(II)無水
英語名
IRON (II) BROMIDE
分子式
Br2Fe
分子量
215.65

名称と別名

Iron(II) bromide7789-46-0UNII-EA3X054RBZEA3X054RBZEINECS 232-168-8RefChem:57875232-168-8Ferrous bromideIron dibromideIRON (II) BROMIDEiron(2+);dibromideMFCD00016081
名称をさらに表示
臭化鉄(II)無水臭化鉄(II)臭化鉄(II), 無水, 98% minFeBr2IRON BROMIDEIron(II)bromide,ultradry,99.995%(metalsbasis)Dibromoironironbromide(febr2)Iron Bromide PowderIron bromide (FeBr2)
Br2FeDibromoiron; Ferrous Bromide,;Iron Dibromide;FERRUM BROMATUMFERROUS BROMIDE, ANHYDROUS, 99.999%SCHEMBL96654FERROUS BROMIDE [MI]FERRUM BROMATUM [HPUS]AKOS015832994

データベース識別子

CAS
7789-46-0
PubChem CID
82240
UNII
EA3X054RBZ
EC Number
232-168-8
Nikkaji
J43.817K

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
3
形式電荷
0
複雑度
0

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesdielectric constant
Physical DescriptionLight yellow to dark brown hygroscopic solid; Soluble in water; [Merck Index] Yellow odorless granules; Hygroscopic and soluble in water; [Alfa Aesar MSDS]

物理化学的性質

融点
684 °C · 684 °C(lit.)
沸点
934 °C · 934 °C(lit.)
比重(密度)
4.63 g/mL · 4.63 g/mL at 25 °C(lit.)
貯蔵温度
2 · Storage temp. 2-8°C
溶解性
エタノール: 非常に溶けやすい (lit.)
外見
ビーズ
色
黄色
比重
4.636 · 4.636
水溶解度
水、THF、メタノール、エタノールに可溶。
Merck
14 · 14,4042
安定性
吸湿性
主な用途
電気めっき材料合成前駆体
InChI
InChI=1S/2BrH.Fe/h2*1H;/q;;+2/p-2
InChIKey
GYCHYNMREWYSKH-UHFFFAOYSA-L

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H302 (11.1%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards SummaryCauses burns; Harmful by ingestion; [Alfa Aesar MSDS] See Iron salts, soluble.
Hazard Classes and CategoriesSkin Corr. 1B (15.6%)

安全と保護具

Threshold Limit Values (TLV)1.0 [mg/m3], as Fe

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 件

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

用途と製造

Uses · 2 件

Used as a polymerization catalyst; [Merck Index]

Iron(II) bromide is useful synthetic intermediate. (L653)

応用分野

一般的な説明This product has been enhanced for catalytic efficiency.

調製方法

製造方法Iron(II) bromide can be prepared by the direct reaction of bromine or hydrogen bromide with iron at red heat.

上流・下流製品情報

下流製品

臭化カルシウム

サプライヤー86 社

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関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
SMILES
[Fe+2].[Br-].[Br-]
CAS データベース
7789 · 7789-46-0(CAS DataBase Reference)
EPAの化学物質情報
Iron bromide (FeBr2) (7789-46-0)

化学的性質

化学的特性鉄IIブロマイドは化学式がFeBr2で表される無機化合物ですこの化合物は鉄のブロミド塩であり鉄イオンが2の酸化状態にあることを示していますこの物質は無色から黄色の結晶または粉末の形態で存在し水や有機溶剤に対して高い溶解性を持っています

化学的特性Yellow to dark brown lumps

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 件

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN3260
hs_code
28275900
risk_code
20-36/37/38
hazard_code
Xn
safety_code
26-36
hazard_class
8
packing_group
III
ストレージクラス
11 - Combustible Solids
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