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四酸化二バナジウム

Vanadium dioxide

HCID 82849
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
12036-21-4
標準SMILES
[O]=[V]=[O]
InChIKey
GRUMUEUJTSXQOI-UHFFFAOYSA-N
分子式
O2V
平均分子量
82.94 g/mol
単同位体質量
82.933787

概要

Vanadium dioxide is a vanadium oxide.

名称と識別子

優先名称
Vanadium dioxide
IUPAC
dioxovanadium
現地名
四酸化二バナジウム
英語名
VANADIUM(IV) OXIDE
分子式
O2V
分子量
82.94

名称と別名

Vanadium dioxide12036-21-4Vanadium oxide (VO2)VO2 cpdDTXSID5065194CHEBI:30047RefChem:193649DTXCID2033603234-841-1601-700-4dioxovanadiumBis(oxido)vanadium
名称をさらに表示
四酸化二バナジウムVANADIUM OXIDEVANADIUM(IV) OXIDEVANADIUM TETRAOXIDE
[VO2]Vanadium Oxide Nanoparticle DispersionEINECS 234-841-1EC 234-841-1SCHEMBL153135AKOS015916218CS-0111597Q421440

データベース識別子

CAS
12036-21-4、12036-73-6
PubChem CID
82849
DTXSID
DTXSID5065194
ChEBI
CHEBI:30047
EC Number
234-841-1、601-700-4
Nikkaji
J2.805.340A、J95.242G

物性

構造計算による物性

極性表面積
34.1 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
3
形式電荷
0
複雑度
18.3

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionBlack crystalline solid; Insoluble in water; [MSDSonline]

物理化学的性質

融点
1970 °C · 1970 °C
比重(密度)
4.33 · 4.33

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 9.3% (22 of 236) of reports.

Warning

H315 (90.3%): Causes skin irritation [Warning Skin corrosion/irritation]

P264, P264+P265, P280, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, and P362+P364 (click each P-code to see the statement)

Aggregated GHS information provided per 236 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 2 件

Chemical: Vanadium oxide (VO2)

REACH registered substance: Vanadium dioxide (EC: 234-841-1)

Hazards SummaryAn irritant; [MSDSonline] See Vanadium pentoxide.
Hazard Classes and CategoriesSkin Irrit. 2 (90.3%)

安全と保護具

Minimum Risk LevelAcute Inhalation: 0.0002 mg/m3 (L134) Intermediate Oral: 0.003 mg/kg/day (L134)

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Vanadium is absorbed mainly via inhalation, though small amounts can be absorbed through the skin and gastrointestional tract. It is rapidly distributed in the plasma, mainly to the kidney, liver, lungs, heart, bone, where it tends to accumulate. With the help of cytochrome P-450 enzymes, it can interconvert between its two oxidation states, vanadyl (V+4) and vanadate (V+5). Both states of vanadium can reversibly bind to transferrin protein in the blood and then be taken up into erythrocytes. Vanadium is excreted mainly in the urine. (L837)

用途と製造

UsesVanadium(IV) oxide, especially in its nanocrystalline form, may find use in glazing applications, extremely fast optical shutters, optical modulators, infrared modulators for missile guidance systems, cameras, and data storage. (L848)
General Manufacturing InformationVanadium oxide (VO2): ACTIVE

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杭州品高化工有限公司0571-87658025 · [email protected]
上海腾准生物科技有限公司19821570922 · [email protected]

関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
Health EffectsBreathing high levels of vanadium affects the lungs, throat, and eyes. Ingestion of vanadium may cause kidney and liver damage, birth defects, or death. (L837)
Exposure RoutesOral (L837) ; inhalation (L837) ; dermal (L837)
Toxicity Summary · 1 件

Vanadium damages alveolar macrophages by decreasing the macrophage membrane integrity, thus impairing the cells' phagocytotic ability and viability. The pentavalent form of vanadium, vanadate, is a potent inhibitor of the Ca+-ATPase and Na+,K+-ATPase of plasma membranes, which decreases intracellular ATP concentration. Vanadium is also believed to induce the production of reactive oxygen species. This may damage DNA and also cause oxidative stress, which can damage the reproductive system. Vanadium also inhibits protein tyrosine phosphatases, producing insulin-like effects. (L837, A247, A248, A249, A250, A251)

Signs and SymptomsInhalation of vanadium causes lung irritation, coughing, wheezing, chest pain, runny nose, and a sore throat. (L837)
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
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