化工社化工社 化学情報印刷レポート · 研究参考用
N-エテニルホルムアミド
N-ビニルホルムアミド · N-エテニルホルムアミド · VFA · SR-497 · N-Vinylformamide · n-ethenyl-formamid · N-ethenyl-Formamide · N-VinylforMaMide 98%
識別子と物理属性
| CAS No. | 13162-05-5 |
|---|---|
| 分子式 | C3H5NO |
| 平均分子量 | 71.08 g/mol |
| 単同位体質量 | 71.03711378 g/mol |
| SMILES | C=CNC=O |
| InChIKey | ZQXSMRAEXCEDJD-UHFFFAOYSA-N |
| PubChem CID | 83191 |
| EC No. | 236-102-9 |
| DTXSID | DTXSID9065366 |
| 現地名 | N-エテニルホルムアミド |
化学・物理的性質
| XLogP | 0 |
|---|---|
| 極性表面積 | 29.1 |
| 水素結合供与体数 | 1 |
| 水素結合受容体数 | 1 |
| 回転可能結合数 | 1 |
| 重原子数 | 5 |
| 形式電荷 | 0 |
| 複雑度 | 42.2 |
| 密度 | 1.014 @25 °C1.014 g/mL at 25 °C (lit.) |
| 沸点 | 210 °C @760 [mm Hg]210 °C (lit.) |
| 蒸気圧 | 0.1 [mm Hg] @25 °C~0.1 mm Hg ( 25 °C) |
| Physical Description | Liquid |
| 融点 | -16 °C (lit.) |
| 屈折率 | n20/D 1.494(lit.) |
| 引火点 | 216 °F |
| 貯蔵条件 | 2-8°C |
| 溶解度 | Soluble in water |
| 外観・状態 | clear liquid |
| pKa（酸解離定数） | 14.70±0.23(Predicted) |
| 色 | Colorless to Amber to Dark green |
| InChI | InChI=1S/C3H5NO/c1-2-4-3-5/h2-3H,1H2,(H,4,5) |
| InChIKey | ZQXSMRAEXCEDJD-UHFFFAOYSA-N |
| SMILES | C(NC=C)=O |
| LogP（分配係数） | -0.11 at 24℃ |
| EPAの化学物質情報 | Formamide, N-ethenyl- (13162-05-5) |
安全性と法規制
| GHS 分類 | This chemical does not meet GHS hazard criteria for 17.2% (36 of 209) of reports.DangerH302 (82.8%): Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P354+P338, P317, P319, P321, P330, P332+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 209 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 規制情報 | Chemical: Formamide, N-ethenyl-Formamide, N-ethenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Formamide, N-ethenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 22-12-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/15886 |
| Hazard Classes and Categories | Acute Tox. 4 (82.8%) |
| Protective Action Criteria (PAC) | 3.0 [mg/m3]33 [mg/m3]200 [mg/m3] |
| 水環境危害等級（WGK） | - |
| TSCA 収載状態 | TSCA listed |
| 税関コード | 2924.19.1150 |
| 危険文句（R） | 61-22-37/38-41-40 |
| 化審法 | (2)-3501 |
| 消防法 | 危-4-3-III |
| 危険表示 | T |
| 安全措置（S） | 53-26-36/37/39-45 |
| 危険等級 | Acute Tox. 4 OralCarc. 2Eye Dam. 1Repr. 1BSkin Irrit. 2STOT SE 3 |
| 貯蔵分類 | 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects |
用途
使用
NVF can be used in the free radical polymerization formation of poly(NVF) with a molecular weight ranging from 104 to 106.
一般的な説明
N-Vinylformamide (NVF) is a class of N-vinylamide that is a precursor to amide and amine functional polymer. It has attractive properties that include high reactivity in polymerization and hydrolysis.