1,2-Bis(dibromomethyl)benzene (HCID 83234)

名称と識別子

優先名称: 1,2-Bis(dibromomethyl)benzene
IUPAC: 1,2-bis(dibromomethyl)benzene
現地名: α,α,α',α'-テトラブロモ-o-キシレン
英語名: alpha,alpha,alpha',alpha'-Tetrabromo-o-xylene
分子式: C8H6Br4
分子量: 421.75

名称と別名

1,2-Bis(dibromomethyl)benzene13209-15-9alpha,alpha,alpha',alpha'-Tetrabromo-o-xyleneBenzene, 1,2-bis(dibromomethyl)-EINECS 236-176-2UNII-3WG2H68VX4NSC 386073WG2H68VX4NSC-38607o-Xylene, alpha,alpha,alpha',alpha'-tetrabromo-DTXSID7022255o-Xylene, .alpha.,.alpha.,.alpha.',.alpha.'-tetrabromo-

名称をさらに表示

α,α,α',α'-テトラブロモ-o-キシレン1,2-ビス(ジブロモメチル)ベンゼン1,2-フェニレンビス(ジブロモメタン)Α,Α,Α′,Α′-テトラブロモ-O-キシレンo-キシリレンテトラブロミドΑ,Α,Α′,Α′‐テトラブロモ‐O‐キシレン′-Tetrabromo-o<1,2-Bis(dibromomethyl)O-XYLYLENE TETRABROMIDEAAAATETRABROMOORTHOXYLENEa,a,a,a-Tertabromo-O-Xylene1,2-bis(dibromomethyl)-benzeà,à,à',à'-tetrabromo-o-xyleneA,A,A',A'-TETRABROMO-O-XYLENE

.alpha.,.alpha.,.beta.,.beta.-Tetrabromo-o-xylene.alpha.,.alpha.,.alpha.',.alpha.'-Tetrabromo-o-xylene.alpha.,.alpha.,.alpha.1,.alpha.1-Tetrabromo-o-xylenealpha,alpha,beta,beta-Tetrabromo-o-xyleneRefChem:71730a,a,a'a'Tetrabromooxylene1,2Bis(dibromomethyl)benzeneDTXCID102255

データベース識別子

CAS: 13209-15-9
PubChem CID: 83234
DTXSID: DTXSID7022255
UNII: 3WG2H68VX4
EC Number: 236-176-2
Nikkaji: J31.710A

物性

構造計算による物性

XLogP: 4.8
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 2
重原子数: 12
形式電荷: 0
複雑度: 119

実験および物理化学的性質

Physical DescriptionLight brown crystalline solid; [Sigma-Aldrich MSDS]

物理化学的性質

融点: 114 · 114-116 °C(lit.)
沸点: 303.01 °C · 303.01°C (rough estimate)
比重(密度): 2.2654 · 2.2654 (rough estimate)
屈折率: 1.704 · 1.7040 (estimate)
貯蔵温度: 30 °C · Store below +30°C.
外見: 液体または低融点固体
色: 無色透明～黄色
水溶解度: 不溶性
BRN: 2211698 · 2211698
InChI: InChI=1S/C8H6Br4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4,7-8H
InChIKey: LNAOKZKISWEZNY-UHFFFAOYSA-N
SMILES: C1(C(Br)Br)=CC=CC=C1C(Br)Br
CAS データベース: 13209 · 13209-15-9(CAS DataBase Reference)
EPAの化学物質情報: 1 · 1,2-Bis(dibromomethyl)benzene (13209-15-9)

化学的性質

化学的特性OFF-WHITE TO GREY CRYSTALLINE POWDER

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (89.1%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H335 (93.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H400 (84.8%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

P260, P261, P264, P264+P265, P271, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information1,2-Bis(dibromomethyl)-benzene: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryCauses burns and lachrymation; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS]

Hazard Classes and CategoriesSkin Corr. 1B (100%)；Eye Dam. 1 (89.1%)；STOT SE 3 (93.5%)；Aquatic Acute 1 (84.8%)

毒性情報

Adverse EffectsDermatotoxin - Skin burns.；Lacrimator (Lachrymator) - A substance that irritates the eyes and induces the flow of tears.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

法規制情報

Regulatory Information1,2-Bis(dibromomethyl)-benzene: Does not have an individual approval but may be used under an appropriate group standard

安全データ

F: 19-21
wgk: 3
tsca: TSCA listed
ridadr: UN 3261 8/PG 2
hs_code: 29039990
risk_code: 34-36/37-20/21/22
hazard_code: C
safety_code: 26-36/37/39-45
hazard_class: 8
packing_group: II
Hazard Classifications: Aquatic Acute 1Eye Dam. 1Skin Corr. 1BSTOT SE 3
ストレージクラス: 8A - Combustible corrosive hazardous materials

化学と産業

用途と製造

General Manufacturing InformationBenzene, 1,2-bis(dibromomethyl)-: ACTIVE

応用分野 · 1 件

使用α,α,α',α'-Tetrabromo-o-xylene reacts with 5endo,6endo-bis-chlormethyl-norborn-2-en to obtain trans/cis-2,3-bis(chloromethyl)-1,4-methano-1,2,3,4-tetrahydroanthracene. Further, it is involved in the preparation of 1-(3-butenyl)-2-(deuteriomethyl)benzene by reacting with allylmagnesium bromide. In addition this, it is used to prepare exo-benzocyclobuteno-1,2,3,4-tetrahydro-1,4-methanoanthracene by reacting with exo-1,4,4a,8b-tetrahydro-1,4-methanobiphenylene.