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ガリウムトリブロミド

Gallium bromide (GaBr3)

HCID 83477
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
13450-88-9
標準SMILES
[Br][Ga]([Br])[Br]
InChIKey
SRVXDMYFQIODQI-UHFFFAOYSA-K
分子式
Br3Ga
平均分子量
309.44 g/mol
単同位体質量
305.68059

概要

Gallium(III) bromide is a chemical compound of gallium and bromine. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625)

名称と識別子

優先名称
Gallium bromide (GaBr3)
IUPAC
tribromogallane
現地名
ガリウムトリブロミド
英語名
GALLIUM(III) BROMIDE
分子式
Br3Ga
分子量
309.43

名称と別名

Gallium(III) bromide13450-88-9Gallium bromide (GaBr3)tribromogallaneGaBr3Gallium bromideTribromogalliumGallium (III) Bromide, anhydrousEINECS 236-609-5NSC 94001Gallium bromide, GaBr3SCHEMBL150912
名称をさらに表示
ガリウムトリブロミド臭化ガリウム三臭化ガリウム臭化ガリウム(Ⅲ)臭化ガリウム(III)臭化ガリウム(III), 無水, granular (99.999%-Ga) PURATREMribromogallaneGALLIUM TRIBROMIDEGallium(lll) bromidegalliumbromide(gabr3)Gallium(III) Tribromide
DTXSID2065466Gallium(III) bromide, ultra dryNSC94001Gallium(III) bromide, 99.999%NSC-94001Q2175117Gallium(III) bromide, anhydrous, powder, 99.999% trace metals basisGallium(III) bromide, ultra dry, 99.99% (metals basis), crystalline, ampouled

データベース識別子

CAS
13450-88-9
PubChem CID
83477
DTXSID
DTXSID2065466

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
4
形式電荷
0
複雑度
8

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionWhite, odorless crystalline solid; [MSDSonline]

物理化学的性質

融点
121.5 °C · 121.5 °C(lit.)
沸点
279 °C · 279 °C(lit.)
比重(密度)
3.69 g/mL · 3.69 g/mL at 25 °C(lit.)
闪点
278.8 °C · 278.8°C
貯蔵温度
2 · under inert gas (nitrogen or Argon) at 2-8°C
溶解性
2 O: · H2O: わずかに溶ける(lit.)
外見
粉
色
白い
比重
3.69 · 3.69
水溶解度
水に溶ける。
安定性
安定ですが、水と激しく反応します。水、湿気、強力な酸化剤との接触を避ける。空気中で変色することがあります。
主な用途
電気めっき材料合成前駆体
InChI
1S/3BrH.Ga/h3*1H;/q;;;+3/p-3
InChIKey
SRVXDMYFQIODQI-UHFFFAOYSA-K
SMILES
Br[Ga](Br)Br
CAS データベース
13450 · 13450-88-9(CAS DataBase Reference)

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 2 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory InformationChemical: Gallium bromide (GaBr3)
Other Safety InformationEvaluation - Chemicals not considered for in depth evaluation - Not commercially active in Australia
Hazards SummaryReacts violently with water; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Bromine.
Hazard Classes and CategoriesSkin Corr. 1B (100%)

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 件

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

用途と製造

General Manufacturing InformationGallium bromide (GaBr3): INACTIVE

応用分野

使用Gallium(III) bromide is used as organic intermediates. It is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes.

上流・下流製品情報

下流製品

トリフルオロメタンスルホン酸ガリウム(III)

サプライヤー47 社

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関連反応

0 件
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現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
EC Number
236-609-5
EPAの化学物質情報
Gallium bromide (GaBr3) (13450-88-9)

化学的性質

化学的特性white crystalline powder

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 件

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 2
hs_code
2827590000
risk_code
14-34
hazard_code
C
safety_code
8-26-36/37/39-45
hazard_class
8
packing_group
II
Hazard Classifications
Skin Corr. 1B
ストレージクラス
8A - Combustible corrosive hazardous materials
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