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ペンタブロモタンタル(V)

Tantalum bromide

HCID 83480
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
13451-11-1
標準SMILES
[Br][Ta]([Br])([Br])([Br])[Br]
InChIKey
GCPVYIPZZUPXPB-UHFFFAOYSA-I
分子式
Br5Ta
平均分子量
580.47 g/mol
単同位体質量
575.53969

概要

Tantalum(V) bromide is a chemical compound of tantalum and bromine. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625)

名称と識別子

優先名称
Tantalum bromide
IUPAC
pentabromotantalum
現地名
ペンタブロモタンタル(V)
英語名
TANTALUM (V) BROMIDE
分子式
Br5Ta
分子量
580.47

名称と別名

Tantalum(V) bromideTantalum pentabromidepentabromotantalumTantalum bromide (TaBr5)VX8APQ3732DTXSID1065471EINECS 236-618-4di-mu-bromido-bis(tetrabromidotantalum(V))di-mu-bromido-bis[tetrabromidotantalum(V)]RefChem:187396DTXCID5034226236-618-4
名称をさらに表示
五臭化タンタルペンタブロモタンタル(V)タンタルペンタブロミドタンタル(V)ブロミドタンタル(V)ペンタブロミド臭化タンタル(V)臭化タンタル(V) (99.9%-Ta)Tantalum(Ⅴ)bromidetantalumbromide(tabr5)Tantalum(V)pentabromideTantalum (V) bromide, 99.99%Tantalum (V) bromide (99.9%-Ta)
266-599-867182-65-4EINECS 266-599-8tantalum bromide13451-11-1TANTALUM (V) BROMIDEtantalum(5+) pentabromideUNII-VX8APQ3732

データベース識別子

CAS
13451-11-1、67182-65-4
PubChem CID

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
37.1

物理化学的性質

融点
240 °C · 240 °C(lit.)
沸点
348 · 348,8°C
比重(密度)
4.989 g/mL · 4.989 g/mL at 25 °C(lit.)
外見
粉
色
黄色
比重
4.989 · 4.989
水溶解度
水に不溶。
CAS データベース
13451 · 13451-11-1(CAS DataBase Reference)
EPAの化学物質情報
Tantalum bromide (TaBr5) (13451-11-1)

化学的性質

化学的特性yellow crystal(s) powder(s); sensitive to moisture; enthalpy of vaporization 62.3 kJ/mol; enthalpy of fusion 45.60 kJ/mol; can be prepared by heating tantalum metal in pure bromine gas above 300°C [STR93] [CRC10]

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H302 (98.5%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P262, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 66 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesAcute Tox. 4 (98.5%)

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

用途と製造

General Manufacturing InformationTantalum bromide (TaBr5): ACTIVE

応用分野

使用The Tantalum Bromide Cluster is used for the preparation of heavy-atom derivatives for structure determination of biological macromolecules by X-ray analysis.

上流・下流製品情報

上流原料

四臭化炭素臭化水素酸酸化タンタルタンタル

サプライヤー24 社

北京华美互利生物化工010-56205725 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海迈瑞尔生化科技有限公司

関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
83480
DTXSID
DTXSID1065471
UNII
VX8APQ3732
EC Number
236-618-4、266-599-8
Exposure Routes
Oral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 件

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 2
risk_code
20/21/22-34
hazard_code
C
safety_code
22-26-27-36/37/39-45
hazard_class
8
packing_group
III
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