Ethanedioyl dibromide (HCID 84841)

名称と識別子

優先名称: Ethanedioyl dibromide
IUPAC: oxalyl dibromide
現地名: 1,2-ジブロモエタン-1,2-ジオン
英語名: OXALYL BROMIDE
分子式: C2Br2O2
分子量: 215.83

名称と別名

Oxalyl bromideEthanedioyl dibromide15219-34-8oxalyl dibromideEthanedioyl bromideoxalylbromideMFCD00000113YZQ2D2RT2QNSC-96957NSC 96957C2Br2O2BrCOCOBr

名称をさらに表示

しゅう酸ジブロミドジブロモエタンジオンオキサリルジブロミド1,2-ジブロモエタン-1,2-ジオン臭化オキサリルオキサリルブロミドオキサリルブロミド溶液レプチンラット由来シュウ酸ジブロミドOBLEPDCAD11CDHOBOXALYL BROMOOxaly bromideOxayl Bromide

EINECS 239-271-7Oxalyl bromide, 97%UNII-YZQ2D2RT2QSCHEMBL186868DTXSID9065869NSC96957AKOS015901745AS-85803

データベース識別子

CAS: 15219-34-8
PubChem CID: 84841
DTXSID: DTXSID9065869
UNII: YZQ2D2RT2Q
EC Number: 239-271-7
Nikkaji: J218.380C

物性

構造計算による物性

XLogP: 1.8
極性表面積: 34.1 Å²
水素結合供与体数: 0
水素結合受容体数: 2
回転可能結合数: 1
重原子数: 6
形式電荷: 0
複雑度: 75.5

実験および物理化学的性質

Chemical ClassesOther Classes -> Halogenated Ketones

SpringerMaterials PropertiesSchoenflies notation

Physical DescriptionClear dark yellow liquid; [Sigma-Aldrich MSDS]

物理化学的性質

融点: -19 °C · -19 °C (lit.)
沸点: 16 · 16-17 °C/10 mmHg (lit.)
比重(密度): 1.517 g/mL · 1.517 g/mL at 25 °C
屈折率: 20 · n20/D 1.522(lit.)
闪点: -19 °C · -19°C
貯蔵温度: 2 · 2-8°C
溶解性: Benzene (Slightly), Chloroform
外見: 液体
色: クリア
由来生物: goat
BRN: 1744437 · 1744437
安定性: Moisture Sensitive
InChI: InChI=1S/C2Br2O2/c3-1(5)2(4)6
InChIKey: JAZLVNXWYDFQFE-UHFFFAOYSA-N
SMILES: C(Br)(=O)C(Br)=O
CAS データベース: 15219 · 15219-34-8
EPAの化学物質情報: Ethanedioyl dibromide (15219-34-8)

化学的性質

化学的特性clear yellow to yellow-green liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards SummaryReacts violently with water; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by inhalation; [Sigma-Aldrich MSDS]

Hazard Classes and CategoriesSkin Corr. 1B (100%)

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

F: 8-9
wgk: 3
tsca: TSCA listed
ridadr: UN 3265 8/PG 2
hs_code: 29171990
risk_code: 23/24/25-34-40-29-20-14-37
hazard_code: C,T
safety_code: 26-36/37/39-45-28-27
hazard_class: 8
packing_group: II
Hazard Classifications: Acute Tox. 4 InhalationEye Dam. 1Skin Corr. 1B
ストレージクラス: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials

化学と産業

用途と製造

General Manufacturing InformationEthanedioyl dibromide: ACTIVE

応用分野 · 1 件

使用Used in synthetic applications of carbon-substituted iminium saltsReactant for:Synthesis of mutasynthons added to cultures of A. pretiosum for mutasynthetic generation of ansamitocin derivativesOxalic acid formation from hydroxyl radical substitutionsCyclization to produce CRF1 receptor antagonistsPreparation, optical and electrochemical studies of thiophene end capped olig(2,3-alkylthieno[3,4-b]pyrazine)Asymmetrical synthesis of glycosyl chlorides and bromides