[(トリメチルシリル)メチル]アミン

1-(Trimethylsilyl)methylamine

HCID 87488CAS 18166-02-4

部分構造検索類似構造を探す

基本情報

標準SMILES: C[Si](C)(C)CN
InChIKey: YVWPNDBYAAEZBF-UHFFFAOYSA-N
分子式: C4H13NSi
平均分子量: 103.24 g/mol
単同位体質量: 103.08172595

名称と識別子

優先名称: 1-(Trimethylsilyl)methylamine
IUPAC: trimethylsilylmethanamine
現地名: [(トリメチルシリル)メチル]アミン
英語名: (Trimethylsilyl)methylamine
分子式: C4H13NSi
分子量: 103.24

名称と別名

1-(Trimethylsilyl)methylamineEINECS 242-049-2DTXSID30171176NSC 96778RefChem:428852DTXCID2093667242-049-218166-02-4(Aminomethyl)trimethylsilane(Trimethylsilyl)methylaminetrimethylsilylmethanamine(trimethylsilyl)methanamine

名称をさらに表示

(トリメチルシリル)メタンアミン(アミノメチル)トリメチルシラントリメチルシリルメタンアミンα-(トリメチルシリル)メタンアミン[(トリメチルシリル)メチル]アミン(トリメチルシリル)メチルアミントリメチルシリルメチルアミンAMTMSrimethylsilylmethanamineTrimethylsilylmethaneamine2-AMINOMETHYLTRIMETHYLSILANEMethylamine, 1-(trimethylsilyl)-,

aminomethyltrimethylsilaneTrimethylsilylmethylamineMethanamine, 1-(trimethylsilyl)-1-(trimethylsilyl)methanamineMFCD00042931Y4CS778E5BNSC-96778NSC96778

データベース識別子

CAS: 18166-02-4
PubChem CID: 87488
DTXSID: DTXSID30171176
ChEMBL: CHEMBL76074
UNII: Y4CS778E5B
EC Number: 242-049-2
Nikkaji: J260.904E

物性

構造計算による物性

極性表面積: 26 Å²
水素結合供与体数: 1
水素結合受容体数: 1
回転可能結合数: 1
重原子数: 6
形式電荷: 0
複雑度: 37.3

実験および物理化学的性質

SpringerMaterials Properties29Si nuclear magnetic resonance spectrum

物理化学的性質

融点: 0 °C · <0°C
沸点: 92 · 92-94 °C(lit.)
比重(密度): 0.771 g/mL · 0.771 g/mL at 20 °C(lit.)
屈折率: 20 · n20/D 1.416
闪点: 9 °C · 9°C
貯蔵温度: Keep in dark place,Inert atmosphere,Room temperature
外見: liquid
酸解離定数(Pka): 10.89 · 10.89±0.10(Predicted)
比重: 0.7697 · 0.7697
BRN: 1731488 · 1731488
InChI: InChI=1S/C4H13NSi/c1-6(2,3)4-5/h4-5H2,1-3H3
InChIKey: YVWPNDBYAAEZBF-UHFFFAOYSA-N
SMILES: C([Si](C)(C)C)N
CAS データベース: 18166 · 18166-02-4(CAS DataBase Reference)
NISTの化学物質情報: Trimethylsilylmethylamine(18166-02-4)

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

安全データ

F: 3-10
wgk: 3
tsca: No
ridadr: UN 2733 3/PG 2
risk_code: 11-34-37
hazard_code: F,C
safety_code: 16-26-36/37/39-45
hazard_class: 3.1
packing_group: II
Hazard Classifications: Flam. Liq. 2Skin Corr. 1B
ストレージクラス: 3 - Flammable liquids

化学と産業

調製方法 · 1 件

純化方法A possible contaminant is hexamethyldisiloxane. It should have two 1H NMR signals in CDCl3; if not, dissolve it in *C6H6, shake it with 15% aqueous KOH, separate, dry (Na2SO4), filter, evaporate and distil it using a still of ca 10 theoretical plates. The water azeotrope has b 83o/735mm; hence it is important to dry the extract well. The hydrochloride has m 198-199o (from MeOH or Me2CO). [Noll et al. J Am Chem Soc 73 3867 1951, Beilstein 4 IV 3878.]