Triethanolamine Lauryl Sulfate (HCID 8777)

概要

Dodecyl sulfate, [triethanolamine salt] is a colorless liquid with a mild odor, Sinks and mixes with water. (USCG, 1999)

名称と識別子

優先名称: Triethanolamine Lauryl Sulfate
IUPAC: 2-[bis(2-hydroxyethyl)amino]ethanol;dodecyl hydrogen sulfate

名称と別名

TRIETHANOLAMINE LAURYL SULFATE139-96-8TEA-Lauryl sulfateDreneTexapon THTea lauryl sulfateSterling watSulfetal ltDodecyl sulfate triethanolamine saltStandapol TPropaste TRichonol T

名称をさらに表示

Akyposal TLSCycloryl WATMaprofix TLSStepanol WATCycloryl TAWFSipon LTMelanol LP20TMaprofix TLS 65

データベース識別子

CAS: 139-96-8
PubChem CID: 8777
DTXSID: DTXSID4027076
ChEMBL: CHEMBL3187366
UNII: E8458C1KAA
EC Number: 205-388-7

物性

構造計算による物性

極性表面積: 136 Å²
水素結合供与体数: 4
水素結合受容体数: 8
回転可能結合数: 18
重原子数: 27
形式電荷: 0
複雑度: 299

実験および物理化学的性質

Chemical ClassesOther Uses -> Emulsifiers/Surfactants

Cosmetics · 2 件

Cosmetic ingredients (TEA-Lauryl Sulfate) -> CIR (Cosmetic Ingredient Review)

Emulsifying; Foaming; Cleansing; Surfactant

pHLiquid pH = 7.0-7.5

Density · 2 件

greater than 1.1 at 68 °F (est.) (USCG, 1999)

Liquid density = 8.8 lbs/gal

Color/FormLIQUID OR PASTE

Animal DrugsPharmaceuticals -> UK Veterinary Medicines Directorate List

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H315 (97.9%): Causes skin irritation [Warning Skin corrosion/irritation]

P264, P264+P265, P280, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P332+P317, P337+P317, and P362+P364 (click each P-code to see the statement)

Aggregated GHS information provided per 234 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 3 件

Chemical: Sulfuric acid, monododecyl ester, compound with 2,2',2''-nitrilotris[ethanol] (1:1)

Sulfuric acid, monododecyl ester, compd. with 2,2',2''-nitrilotris[ethanol] (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, monododecyl ester, compd. with 2,2',2''-nitrilotris[ethanol] (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Sulfuric acid, monododecyl ester, compd. with 2,2',2''-nitrilotris[ethanol] (1:1): Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsSpecial Hazards of Combustion Products: Toxic vapors of triethanolamine and oxides of nitrogen may form in fire. (USCG, 1999)

Health HazardsIngestion causes mild irritation of stomach. Contact with liquid irritates eyes and causes some corneal damage if prolonged. Skin is mildly irritated on prolonged contact. (USCG, 1999)

Hazards SummaryAn eye irritant; May cause corneal damage on prolonged contact; [CAMEO] A skin and eye irritant, based on animal studies; [IUCLID] An irritant; May cause serious eye injury; [MSDSonline] See Triethanolamine.

Reactive GroupAlcohols and Polyols

Reactivity ProfileReacts violently with strong oxidants [Handling Chemicals Safely, 1980 p. 928]. Toxic vapors of triethanolamine and oxides of nitrogen may form in fire (USCG, 1999).

安全と保護具

First AidINGESTION: consult a doctor if large amount was ingested.

Disposal Methods · 1 件

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Personal Protective Equipment (PPE)Rubber gloves; goggles or face shield (USCG, 1999)

毒性情報

Toxicity Summary · 2 件

The CIR Expert Panel concluded that TEA and the 31 related TEA-containing ingredients are safe in the present practices of use and concentration described in this safety assessment when formulated to be nonirritating and when the levels of free diethanolamine do not exceed the present practices of use and concentration of diethanolamine itself. These ingredients should not be used in cosmetic products in which N-nitroso compounds can be formed...TEA-Lauryl Sulfate...

Safe for use in cosmetics, with qualifications

Human Toxicity Excerpts...INJURIES OF EYE RESULTING FROM SPLASH CONTAMINATION WITH ANIONIC SURFACTANTS ARE LESS SERIOUS THAN THOSE FROM CATIONIC, BUT MAY ENTAIL MORE DISCOMFORT & IRRITATION THAN FROM NONIONIC SURFACTANTS. /ANIONIC SURFACTANTS/

Non-Human Toxicity Excerpts · 4 件

...TESTED AT 0.5%-1% CONCN IN WATER BY APPLICATION OF DROP TO RABBIT EYES TYPICALLY HAS CAUSED IMMEDIATE DISCOMFORT, HYPEREMIA OF CONJUNCTIVA, EDEMA OF CORNEAL EPITHELIUM WITH PUNCTATE STAINABILITY BY FLUORESCEIN...PROMPT HEALING IN DAY OR TWO...NO OPACITY. /ANIONIC SURFACTANTS/

WIDELY USED ANIONIC DETERGENTS OF LOW ACUTE & CHRONIC TOXICITY. FEW OF BRANCHED-CHAIN PRODUCTS...SHOWN...SIGNIFICANT PERCUTANEOUS TOXICITY. SKIN IRRITATION MAY BE ENCOUNTERED WITH ANY OF THESE SUBSTANCES. /ALKYL SODIUM SULFATES/

TEALS WAS AMONG SURFACTANT CMPD TESTED FOR IRRITANCY WITH CRITERIA INCL SENSORY RESPONSE, PAIN/DISCOMFORT OR TISSUE DAMAGE IN ANIMALS. TEALS WAS MOST IRRITATING IN TEST WITH MOUSE UPPER RESP TRACT, WRITHING TESTS & DRAIZE SKIN TEST.

HALF OF LABORATORIES SCORED 46% AQ TRIETHANOLAMINE LAURYL SULFATE AS IRRITANT & HALF SCORED IT AS NONIRRITANT WITH SKIN IRRITATION TESTS ON RABBITS.

化学と産業

用途と製造

Uses · 6 件

CIR ingredient: TEA-Lauryl Sulfate

Used as surfactant for firefighting foams, textile auxiliary and dye dispersant, wetting, foaming, and dispersing agent (industrial, cosmetics, and pharmaceuticals), detergent (hair dyes, cosmetics, and industrial and household cleaners), and emulsifier in emulsion polymerizations; [HSDB] Used for refining and processing of metals; [IUCLID]

Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

Surfactant for fire fighting foams, textile auxiliary.

WETTING, FOAMING & DISPERSING AGENT FOR INDUSTRIAL, COSMETIC & PHARMACEUTICAL APPLICATIONS, ESP SHAMPOOS

SHAMPOO, BUBBLE BATH BASE; DETERGENT IN HAIR DYES AND OTHER COSMETICS; DETERGENT IN INDUSTRIAL & HOUSEHOLD CLEANERS; PIGMENT DISPERSANT; EMULSIFIER IN EMULSION POLYMERIZATIONS

U.S. Production · 3 件

2023: 75,000 - <500,000 lb

(1972) 7.29X10+9 GRAMS

(1976) 2.52X10+9 GRAMS

Consumer UsesFlame retardant

Industry UsesSurfactant (surface active agent)

Methods of ManufacturingSULFATION OF DODECYL ALCOHOL WITH SULFURIC ACID OR CHLOROSULFONIC ACID, FOLLOWED BY NEUTRALIZATION WITH TRIETHANOLAMINE

Formulations/Preparations · 4 件

Liquid or paste

Maprofix TLS contains 65% triethanolamine lauryl sulfate

Available as a 40% active liquid

Milky Bath Bubbles contain triethanolamine lauryl sulfate

Triethanolamine Lauryl Sulfate

基本情報

概要