9H-Fluorene-9-methanol (HCID 90466)

名称と識別子

優先名称: 9H-Fluorene-9-methanol
IUPAC: 9H-fluoren-9-ylmethanol
現地名: 9-フルオレニルメタノール
英語名: 9-Fluorenemethanol
分子式: C14H12O
分子量: 196.24

名称と別名

24324-17-29H-Fluorene-9-methanolFluorene-9-methanol(Fluoren-9-yl)methanolEINECS 246-167-5DTXSID7066980RefChem:549969DTXCID1037064246-167-59-Fluorenemethanol9-Fluorenylmethanol9H-Fluoren-9-ylmethanol

名称をさらに表示

9-フルオレニルメタノール9H-フルオレン-9-メタノール9-ヒドロキシメチル-9H-フルオレン9-フルオレンメタノル9フルオレニルメタノ-ル9-フルオレンメタノール9-ヒドロキシメチルフルオレン9‐フルオレンメタノール9-フルオレニルメタノール, 99%(フルオレン-9-イル)メタノール(9H-フルオレン-9-イル)メタノール9H-フルオレン-9-イルメタノールFMOC-OHFMOLFM-OHFoMc-OHFluorenemethanolFLUORENYL METHANOLHOFMFMOC-hydroxy

(9h-fluoren-9-yl)methanol9-(Hydroxymethyl)fluorene9-HydroxymethylfluoreneMFCD000011399-Fluorenyl Methanolfluoren-9-ylmethan-1-ol9-fluorenmethanol9-FluorenYl-Methanol

データベース識別子

CAS: 24324-17-2
PubChem CID: 90466
DTXSID: DTXSID7066980
UNII: AWJ7E4RKJ8
EC Number: 246-167-5
Nikkaji: J208.517H

物性

構造計算による物性

XLogP: 2.7
極性表面積: 20.2 Å²
水素結合供与体数: 1
水素結合受容体数: 1
回転可能結合数: 1
重原子数: 15
形式電荷: 0
複雑度: 203

実験および物理化学的性質

LogP2.89

Endocrine DisruptorsPotential endocrine disrupting compound

物理化学的性質

融点: 105 · 105-107 °C (lit.)
沸点: 293.14 °C · 293.14°C (rough estimate)
比重(密度): 1.0304 · 1.0304 (rough estimate)
屈折率: 1.5385 · 1.5385 (estimate)
貯蔵温度: Sealed in dry,Room Temperature
溶解性: メタノールに可溶。
外見: 結晶性粉末
酸解離定数(Pka): 13.68 · 13.68±0.10(Predicted)
色: 白色～淡黄色
BRN: 2330017 · 2330017
InChI: InChI=1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2
InChIKey: XXSCONYSQQLHTH-UHFFFAOYSA-N
SMILES: C1(CO)C2=C(C=CC=C2)C2=C1C=CC=C2
CAS データベース: 24324 · 24324-17-2(CAS DataBase Reference)
NISTの化学物質情報: -9 · Fluorene-9-methanol(24324-17-2)
EPAの化学物質情報: 9 H-Fluorene-9-methanol · 9H-Fluorene-9-methanol (24324-17-2)

化学的性質

化学的特性WHITE TO PALE YELLOW CRYSTALLINE POWDER

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

危険有害性情報

Hazard Classes and CategoriesAcute Tox. 4 (100%)

安全データ

wgk: 3
tsca: TSCA listed
hs_code: 29062900
risk_code: 36/37/38
hazard_code: Xi
hazard_note: Irritant
safety_code: 22-24/25-36/37/39-27-26
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

General Manufacturing Information9H-Fluorene-9-methanol: INACTIVE

応用分野 · 3 件

用途有機合成原料、ペプチド合成保護試薬。

使用9-Fluorenylmethanol(FMOC-OH) acts as a N-protecting reagent, which is used in the synthesis of peptide. It is also used in the preparation of deoxynucleoside 9-fluorenemethyl phosphorodithioates. Further, it is used to prepare 9-(fluoromethyl)fluorene. In addition to this, it is involved in the electropolymerization with boron trifluoride diethyl etherate to yield low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) film.

一般的な説明Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method.