CAS 1195-92-2 Limonene oxide (HCID 91496)

概要

Limonene 1,2-epoxide is an epoxide resulting from the formal epoxidation of the cyclic double bond of limonene. It has a role as a plant metabolite. It is a limonene monoterpenoid and an epoxide.

名称と識別子

優先名称: Limonene oxide
IUPAC: 1-methyl-4-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane
現地名: 1-メチル-4-イソプロペニル-1,2-エポキシシクロヘキサン
英語名: (+)-Limonene oxide 97% mixture of cis&
分子式: C10H16O
分子量: 152.23

名称と別名

Limonene oxide1195-92-21-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptane7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)-4-Isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptane(+)-Limonene oxidep-Menth-8-ene, 1,2-epoxy-MFCD000051271-methyl-4-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane1-Methyl-4-(1-methylethenyl)-7-oxabicyclo(4.1.0)heptaneNSC120451-Methyl-4-(1-methylvinyl)-7-oxabicyclo(4.1.0)heptane

名称をさらに表示

リモネン-1,2-オキシドリモネン1,2-オキシド1-メチル-4-イソプロペニル-7-オキサビシクロ[4.1.0]ヘプタン1,2-エポキシ-1-メチル-4-(1-メチルエテニル)シクロヘキサン1,2-エポキシ-1-メチル-4-イソプロペニルシクロヘキサン1-メチル-4-(1-メチルエテニル)-7-オキサビシクロ[4.1.0]ヘプタンリモネンオキシド1,2-エポキシ-p-メンタ-8-エン1-メチル-4-(1-メチルエテニル)-1,2-エポキシシクロヘキサン3-イソプロペニル-6-メチル-7-オキサビシクロ[4.1.0]ヘプタンリモネンエポキシドリモネンモノオキシド酸化(+)-リモネン1-メチル-4-イソプロペニル-1,2-エポキシシクロヘキサン1,2-エポキシリモネン3-(1-メチルエテニル)-6-メチル-7-オキサビシクロ[4.1.0]ヘプタンリモネン-1,2-エポキシドα-リモネン1,2-エポキシドリモネンオキサイドリモネン-1，2-オキサイドLimonene epoxideeneoxyLiMonene oxydelimoneneepoxideD-LIMONENEOXIDElimonenemonoxidelimonene1,2-oxideLimonene monoxideLimonene 1,2-oxide

1-Methyl-4-(1-methylethenyl)-7-oxabicyclo[4.1.0]heptane1-methyl-4-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptane7-Oxabicyclo(4.1.0)heptane, 1-methyl-4-(1-methylethenyl)-CCRIS 3763EINECS 214-805-1NSC 120451-methyl-4-(1-methylethenyl)-7-oxabicyclo(4.1.0)heptan1-methyl-4-(1-methylethenyl)-7-oxabicyclo[4.1.0]heptan

データベース識別子

CAS: 1195-92-2、13837-75-7
PubChem CID: 91496
DTXSID: DTXSID50862594
ChEMBL: CHEMBL2268547
ChEBI: CHEBI:16431
EC Number: 214-805-1
Nikkaji: J236.493J、J27.205A

物性

構造計算による物性

XLogP: 2.5
極性表面積: 12.5 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 1
重原子数: 11
形式電荷: 0
複雑度: 197

実験および物理化学的性質

FragrancesFragrance Ingredient (d-8-p-Menthene-1,2-epoxide) -> IFRA transparency List

Density0.926-0.936 (20 °C)

Solubility · 2 件

Practically insoluble to insoluble in water

Soluble (in ethanol)

Boiling Point198º

Refractive Index1.464-1.474

Physical Description · 2 件

Liquid

Colourless to pale yellow liquid; fresh clean citrus aroma

物理化学的性質

沸点: 113 · 113-114 °C50 mm Hg(lit.)
比重(密度): 0.929 g/mL · 0.929 g/mL at 25 °C(lit.)
FEMA: 4655 · 4655 | D-8-P-MENTHENE-1,2-EPOXIDE
屈折率: 20 · n20/D 1.466(lit.)
闪点: 150 °F · 150 °F
貯蔵温度: 2 · 2-8°C, stored under nitrogen
比重: 0.929 · 0.929
臭い (Odor): 0.3 · シトラスおよびミントのフレーバーに使用: 飲料および乳製品では 0.3 ～ 0.5 ppm、ソースでは最大 5 ppm。注: エポキシドは、酸性条件下ではアルコールおよび水溶液で失われる可能性があります。フレッシュでクリーンなシトラスミントスペアミントハーブ
においのタイプ: 柑橘類
JECFA Number: 2145 · 2145
Henry's Law Constant: 5.6 · 5.6×10-2 mol/(m3Pa) at 25℃, Fichan et al. (1999)
LogP: 2.43 · 2.43
EPAの化学物質情報: 7 · 7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)- (1195-92-2)

化学的性質

化学的特性clear colorless liquid

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 86% (98 of 114) of all reports.

Warning

H315 (14%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P271, P272, P280, P302+P352, P304+P340, P319, P321, P332+P317, P333+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 114 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 3 件

Chemical: 7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)-

7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

7-Oxabicyclo4.1.0heptane, 1-methyl-4-(1-methylethenyl)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and CategoriesSkin Irrit. 2 (14%)

安全データ

wgk: 3
tsca: TSCA listed
毒性: mouse,LD50,intramuscular,100mg/kg (100mg/kg),Journal of Scientific and Industrial Research, Section C: Biological Sciences. Vol. 21, Pg. 342, 1962.

化学と産業

薬理情報

Cellular LocationsExtracellular

用途と製造

U.S. Production2023: 1,000,000 - <5,000,000 lb

Industry UsesOdor agents

Use Classification · 3 件

Fragrance Ingredients

Flavouring Agent -> FLAVOURING_AGENT -> JECFA Functional Classes

Flavoring Agents -> JECFA Flavorings Index

General Manufacturing Information · 2 件

Soap, Cleaning Compound, and Toilet Preparation Manufacturing

7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)-: ACTIVE

応用分野

用途有機合成原料。

上流・下流製品情報

上流原料

2-Cyclohexen-1-ol, 2-methyl-5-(1-methylethenyl)-, (5R)-Oxirane, 2-methyl-2-(4-methyl-3-cyclohexen-1-yl)-2-メチル-5-(1-メチルエテニル)-2-シクロヘキセン-1-オール (±)-リモネン

下流製品

(4R)-1,2-エポキシ-4-(2-メチルオキシラニル)-1-メチルシクロヘキサン

サプライヤー38 社

上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]

上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]

Henan Rane Chemical Co., Ltd.+86-18738066252 · [email protected]

普善实业（陕西）有限公司029-81310890 18165209495 · [email protected]

Suzhou ARTK Medchem Co., Ltd.+86-18168183658 · [email protected]

補足説明

定義ChEBI: An epoxide resulting from the formal epoxidation of the cyclic double bond of limonene.

化合物ノート

読み込み中…

1-メチル-4-イソプロペニル-1,2-エポキシシクロヘキサン

基本情報

概要