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1,1'-メチレンビス(4-グリシジルオキシベンゼン)

Bisphenol F diglycidyl ether

HCID 91511
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基本情報名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
2095-03-6
標準SMILES
c1cc(OCC2CO2)ccc1Cc1ccc(OCC2CO2)cc1
InChIKey
XUCHXOAWJMEFLF-UHFFFAOYSA-N
分子式
C19H20O4
平均分子量
312.4 g/mol
単同位体質量
312.13615911

名称と識別子

優先名称
Bisphenol F diglycidyl ether
IUPAC
2-[[4-[[4-(oxiran-2-ylmethoxy)phenyl]methyl]phenoxy]methyl]oxirane
現地名
1,1'-メチレンビス(4-グリシジルオキシベンゼン)
英語名
BISPHENOL F DIGLYCIDYL ETHER
分子式
C19H20O4
分子量
312.36

名称と別名

Bisphenol F diglycidyl etherCHEBI:142451BFDGE cpdRefChem:917346DTXSID50883204254-641-839817-09-9Methane, bis((2,3-epoxypropoxy)phenyl)-Oxirane, 2,2'-(methylenebis(phenyleneoxymethylene))bis-2095-03-6Bis(4-glycidyloxyphenyl)methanepara-para-BFDGE
名称をさらに表示
4,4'-メチレンビス[1-(グリシジルオキシ)ベンゼン]4,4'-メチレンビス(グリシジルオキシベンゼン)ビス[4-(グリシジルオキシ)フェニル]メタン4,4'-メチレンビス(1-グリシジルオキシベンゼン)1,1'-メチレンビス(4-グリシジルオキシベンゼン)ビス[4-(オキシラニルメトキシ)フェニル]メタンメチレンビス(4,1-フェニレン)ビス(グリシジルエーテル)2,2'-[メチレンビス(4,1-フェニレンオキシメチレン)]ビスオキシラン4,4'-メチレンビス[(グリシジルオキシ)ベンゼン]ビス(4-グリシジルオキシフェニル)メタンビスフェノール F ジグリシジルエーテル, MIXTURE OF DIASTEREOMERSビスフェノール F ジグリシジルエーテル (90%)(MIXTURE OF DIASTEREOMERS)4,4′-メチレンビス[1-(オキシラニルメトキシ)ベンゼン]2,2′-[メチレンビス[(4,1-フェニレンオキシ)メチレン]]ビスオキシラン2,2′-[メチレンビス(4,1-フェニレンオキシメチレン)]ビスオキシラン2,2′-[メチレンビス(1,4-フェニレンオキシメチレン)]ビスオキシラン4,4′-メチレンビス[1-(グリシジルオキシ)ベンゼン]1,1′-メチレンビス(4-グリシジルオキシベンゼン)4,4′-メチレンビス(グリシジルオキシベンゼン)2-{[4-({4-[(オキシラン-2-イル)メトキシ]フェニル}メチル)フェノキシ]メチル}オキシランOxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis-Einecs 218-257-4

データベース識別子

CAS
2095-03-6、39817-09-9
PubChem CID
91511
DTXSID
DTXSID4044872
ChEMBL
CHEMBL3182674
ChEBI
CHEBI:142451
UNII
V3625OQU1K
EC Number
218-257-4、254-641-8
Nikkaji
J298.690F

物性

構造計算による物性補完中

XLogP
3.2
極性表面積
43.5 Ų
水素結合供与体数
0
水素結合受容体数
4
回転可能結合数
8
重原子数
23
形式電荷
0
複雑度
324

実験および物理化学的性質

Physical DescriptionMethylene bis(phenyleneoxymethylene)bisoxirane is a colorless liquid resin.
Kovats Retention Index2704
Collision Cross Section169.0 Ų [M+Na]+ [CCS Type: DT; Buffer gas: N2; Ionization: ESI+; Dataset: TOXCAST; Source Identifier: DTXSID4044872]

物理化学的性質

融点
15 °C · −15 °C(lit.)
沸点
474 · 474.0±25.0 °C(Predicted)
比重(密度)
1.19 g/mL · 1.19 g/mL at 25 °C(lit.)
屈折率
20 · n20/D 1.579(lit.)
闪点
230 °F · >230 °F
貯蔵温度
2 · 2-8°C
溶解性
Chloroform (Slightly), DMSO (Slightly)
外見
Solid
色
White to Off-White
BRN
5349017 · 5349017
主な用途
洗浄剤化粧品食品および飲料パーソナルケア
InChI
InChI=1S/C19H20O4/c1-5-16(20-10-18-12-22-18)6-2-14(1)9-15-3-7-17(8-4-15)21-11-19-13-23-19/h1-8,18-19H,9-13H2

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 4.5% (3 of 66) of reports.

Warning

H315 (95.5%): Causes skin irritation [Warning Skin corrosion/irritation];H317 (95.5%): May cause an allergic skin reaction [Warning Sensitization, Skin];H319 (75.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (68.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H400 (68.2%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (68.2%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard];H411 (27.3%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P261, P264, P264+P265, P271, P272, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 66 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 3 of 66 reports by companies.;There are 5 notifications provided by 63 of 66 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 5 件

Chemical: Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-

Hazard Traits - Endocrine Toxicity;Authoritative List - CECBP - Priority Chemicals;Report - if used as a fragrance or flavor ingredient

Council Directive (EEC) No 109/1989 (Repealed by Reg. EC No 1935/2004 (amended))

Oxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

化学と産業

用途と製造

General Manufacturing InformationOxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-: ACTIVE
応用分野 · 2 件

使用Bisphenol F Diglycidyl Ether is an novalac glycidyl ether (NOGE). Bisphenol F Diglycidyl Ether is found in resin used as coatings for food cans. Bisphenol F Diglycidyl Ether is a toxic conatminant wit h strict limitations on the amount allowed in food products.

一般的な説明Bisphenol F diglycidyl ether (BFDGE) is a stabilizing compound, commonly used as a precursor in the production of epoxy resins and as an additive in organosol resins. It is reported to be used as a material for interior coating of food cans.

上流・下流製品情報

上流原料

エピクロロヒドリン4,4'-ジヒドロキシジフェニルメタン

サプライヤー

読み込み中…

公開中の見積依頼

読み込み中…

関連反応

1 件
反応記録を作成
HRID 972028 の反応式
HRID 972028反応物としてuspto-grants-1979_07

化合物ノート

読み込み中…

このページの内容基本情報名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
Bisphenol A Impurity 9
Bisoprolol Impurity 62
liquid bisphenol F epoxy resins
Bis[4-(glycidyloxy)phenyl]methaneBFDGEp,p-BFDGE2-[[4-[[4-(oxiran-2-ylmethoxy)phenyl]methyl]phenoxy]methyl]oxiraneBis[4-[(oxiran-2-yl)methoxy]phenyl]methaneDiphenylolmethane diglycidyl etherbis(4-(oxiran-2-ylmethoxy)phenyl)methane4,4'-Methylenebisphenol diglycidyl ether
InChIKey
XUCHXOAWJMEFLF-UHFFFAOYSA-N
SMILES
C(C1=CC=C(OCC2CO2)C=C1)C1=CC=C(OCC2CO2)C=C1
EPAの化学物質情報
2 · Oxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis- (2095-03-6)

化学的性質

化学的特性Clear Colourless Oil

Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Fire HazardsFlash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
Reactive GroupEthers;Epoxides
Reactivity ProfileMETHYLENE BIS(PHENYLENEOXYMETHYLENE)BISOXIRANE is incompatible with strong oxidizers.
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and Categories · 2 件

Skin Irrit. 2 (95.5%);Skin Sens. 1 (95.5%);Eye Irrit. 2 (75.8%);STOT SE 3 (68.2%);Aquatic Acute 1 (68.2%);Aquatic Chronic 1 (68.2%);Aquatic Chronic 2 (27.3%)

Skin Irrit. 2 (100%);Skin Sens. 1 (100%);Eye Irrit. 2 (100%);Aquatic Chronic 2 (100%)

安全と保護具

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Nonfire Spill ResponseSTORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)
Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

法規制情報

Regulatory Information · 5 件

Chemical: Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-

Hazard Traits - Endocrine Toxicity;Authoritative List - CECBP - Priority Chemicals;Report - if used as a fragrance or flavor ingredient

Council Directive (EEC) No 109/1989 (Repealed by Reg. EC No 1935/2004 (amended))

Oxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

安全データ

wgk
3
ridadr
UN 3082 9/PG 3
risk_code
36/38-43-50/53-36/37/38
hazard_code
Xi,N
safety_code
37/39-61-60-36/37-26
Hazard Classifications
Aquatic Acute 1Aquatic Chronic 1Eye Irrit. 2Skin Irrit. 2Skin Sens. 1STOT SE 3
ストレージクラス
11 - Combustible Solids