硝酸アニオン
硝酸イオン · ニトラート · 硝酸アニオン · 硝酸塩 · 硝酸性窒素 · ビス(1-ナフチルメチル)アミニウム · ビス[(ナフタレン-2-イル)メチル]アザニウム · ビス(2-ナフチルメチル)アミニウム
識別子と物理属性
| CAS No. | 14797-55-8 |
|---|---|
| 分子式 | NO3- |
| 平均分子量 | 62.005 g/mol |
| 単同位体質量 | 61.98781786 g/mol |
| SMILES | O=[N+]([O-])[O-] |
| InChIKey | NHNBFGGVMKEFGY-UHFFFAOYSA-N |
| PubChem CID | 943 |
| ChEMBL | CHEMBL186200 |
| ChEBI | CHEBI:17632 |
| DTXSID | DTXSID5024217 |
| 現地名 | 硝酸アニオン |
化学・物理的性質
| XLogP | -1.4 |
|---|---|
| 極性表面積 | 62.9 |
| 水素結合供与体数 | 0 |
| 水素結合受容体数 | 3 |
| 回転可能結合数 | 0 |
| 重原子数 | 4 |
| 形式電荷 | -1 |
| 複雑度 | 18 |
| Physical Description | Solid |
| 貯蔵条件 | 2-8°C |
| 外観・状態 | 液体 |
| 色 | 無色透明 |
| 溶解度 | 水と混和します。 |
| InChI | InChI=1S/NO3/c2-1(3)4/q-1 |
| InChIKey | NHNBFGGVMKEFGY-UHFFFAOYSA-N |
| SMILES | [N+]([O-])([O-])=O |
| EPAの化学物質情報 | Nitrate (14797-55-8) |
化学的特性
A colorless liquid.
安全性と法規制
| 規制情報 | Hazard Traits - HematotoxicityAuthoritative List - CA MCLsCWA 303(d)Report - if used as a fragrance or flavor ingredientRegulation (EC) No 1831/2003 (amended) |
|---|---|
| 輸送ラベル（DOT） | Oxidizer |
| 火災危険 | Excerpt from ERG Guide 140 [Oxidizers]:CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (ERG Guide 112). These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. (ERG, 2024) |
| 健康有害性 | Excerpt from ERG Guide 140 [Oxidizers]:Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2024) |
| 反応性グループ | Nitrate and Nitrite Compounds, Inorganic |
| Reactivity Alerts | ExplosiveStrong Oxidizing Agent |
| Reactivity Profile | Mixtures of metal/nonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitratesmixtures of a nitrate with phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979 p. 108-109]. |
| DOT Hazard Classification | Nitrates, inorganic, aqueous solution, n.o.s.UN3218Div 5.1 Oxidizer (49 eCFR § 173.127)PG II: the degree of danger presented by the material is mediumPG III: the degree of danger presented by the material is minorFor more information about the packing group assignment, please visit 49 eCFR § 173Nitrates, inorganic, n.o.s. |
| Air and Water Reactions |
用途
解説
一般式MINO3．一般に，水溶性の無色結晶．加熱すると，最終的に酸素あるいは窒素酸化物を放って分解するので，強い酸化作用がある．
説明
Nitrate is commonly found in drinking water sources especially in agricultural areas where nitrogen fertilizer is used, and where unregulated shallow private wells are more at the risk of contamination. The World Health Organization (WHO) guideline of 50 ppm and the US maximum contaminant level (MCL) of 45 ppm for nitrate in drinking water have been established for protecting infants from methemoglobinemia, commonly known as blue baby syndrome. The health protective value continues to be a subject of public health interest for many years, with varying opinion on whether it is too high or too low. Evaluation of nitrate will need to include consideration of nitrite because both are closely related in the nitrogen cycle in the environment and the body, and nitrite plays a major role in inducing toxicity after its formation from nitrate. More recently, reports of nitrate in drinking water, especially at levels higher than 50 ppm, have been associated with other health effects other than methemoglobinemia. This toxicological review provides an update on the health effects of nitrate with a focus on methemoglobinemia, reproductive and developmental effects, potential carcinogenicity, and especially endocrine/thyroid effects.
使用
In the treatment of angina pectoris; in the manufacture of inorganic and organic nitrates and nitro compounds for fertilizers, dye intermediates, explosives, and many different organic chemicals.
一般的な説明
Crystalline solids. Salts of nitrate, such as ammonium nitrate, potassium nitrate, and sodium nitrate.