N,N,N',N'-テトラメチルベンジジン

N,N,N',N'-Tetramethylbenzidine

HCID 9702CAS 366-29-0
部分構造検索類似構造を探す

基本情報

標準SMILES
CN(C)c1ccc(-c2ccc(N(C)C)cc2)cc1
InChIKey
YRNWIFYIFSBPAU-UHFFFAOYSA-N
分子式
C16H20N2
平均分子量
240.34 g/mol
単同位体質量
240.16264865

名称と識別子

優先名称
N,N,N',N'-Tetramethylbenzidine
IUPAC
4-[4-(dimethylamino)phenyl]-N,N-dimethylaniline
現地名
N,N,N',N'-テトラメチルベンジジン
英語名
N,N,N',N'-Tetramethylbenzidine
分子式
C16H20N2
分子量
240.34

名称と別名

N,N,N',N'-TETRAMETHYLBENZIDINE366-29-0DTXSID0036845N,N,N',N'-Tetramethyl-(1,1'-biphenyl)-4,4'-diamineRefChem:161061DTXCID8016845206-676-5n,n,n,n-tetramethylbenzidineBenzidine, N,N,N',N'-tetramethyl-4,4'-Bis(dimethylamino)biphenylMFCD00008310N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine
名称をさらに表示
N,N,N',N'-テトラメチルベンジジン4,4'-ビス(ジメチルアミノ)-1,1'-ビフェニルN,N,N',N'-テトラメチル-4,4'-ビフェニルジアミンN,N,N',N'-テトラメチル-ビフェニル-4,4'-ジアミンN,N,N',N'-テトラメチルビフェニル-4,4'-ジアミン-N,N,N',N'-テトラメチルビフェニル-4,4'-ジアミン4,4'-ビス(ジメチルアミノ)ビフェニルN,N,N',N'-テトラメチル-1,1'-ビフェニル-4,4'-ジアミンN,N,N',N'-テトラメチル-4,4'-ビアニリンN,N,N′,N′-テトラメチルベンジジンN,N,N′,N′‐テトラメチルベンジジン4,4’-bis(n,n-dimethTIMTEC-BB SBB006258n,n,n’,n’-tetramethyl-benzidin3,5,3'',5''-TETRAMETHYLBENZIDINN,N,N',N'-Tetramethylbenzidine >
4,4'-Bis(N,N-dimethylamino)biphenylN,N,N',N'-Tetramethyl-p,p'-benzidine[1,1'-Biphenyl]-4,4'-diamine, N,N,N',N'-tetramethyl-(1,1'-Biphenyl)-4,4'-diamine, N,N,N',N'-tetramethyl-NSC-4334-[4-(dimethylamino)phenyl]-N,N-dimethylaniline4,4'-Bis(dimethylamino)-1,1'-biphenylCCRIS 1000

データベース識別子

CAS
366-29-0
PubChem CID
9702
DTXSID
DTXSID0036845
ChEMBL
CHEMBL3823639
UNII
2Q6KUH7P3S
EC Number
206-676-5
Nikkaji
J1.527J

物性

構造計算による物性

XLogP
4.6
極性表面積
6.5 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
3
重原子数
18

実験および物理化学的性質

Vapor Pressure0.0000163 [mmHg]
Physical DescriptionSolid; [Sigma-Aldrich MSDS]

物理化学的性質

融点
193 · 193-195 °C(lit.)
沸点
373.06 °C · 373.06°C (rough estimate)
比重(密度)
1.0485 · 1.0485 (rough estimate)
屈折率
1.5519 · 1.5519 (estimate)
貯蔵温度
2 · 2-8°C, protect from light
外見
微粉

化学的性質

化学的特性solid

安全と法規制

GHS分類

GHS Classification · 5 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazards SummaryA skin and strong eye irritant; [Sigma-Aldrich MSDS] See Benzidine.
Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.6%)

安全データ

wgk
3
tsca
TSCA listed
rtecs
DD1752100
毒性
mma-sat 10 nmol/plate EMMUEG 10,263,87
hs_code
29215990
risk_code
36/37/38-40-22

化学と産業

用途と製造

General Manufacturing Information[1,1'-Biphenyl]-4,4'-diamine, N4,N4,N4',N4'-tetramethyl-: INACTIVE
調製方法 · 1 件

純化方法Crystallise the benzidine from EtOH or pet ether, then from pet ether/*benzene, and sublime it in a vacuum. [Guarr et al. J Am Chem Soc 107 5104 1985.] Dry it in vacuo in a drying pistol, or a vacuum line. It has m 195-196o after sublimation. [Beilstein 13 H 221, 13 I 61, 13 II 97, 13 III 429, 13 IV 368.]

上流・下流製品情報

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
上海衡新化工科技有限公司13917104483; 13917104483 · [email protected]

関連反応

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