CAS 10031-43-3 Copper(II) nitrate trihydrate (HCID 9837674)

概要

See also: Copper (II) nitrate, trihydrate (annotation moved to).

名称と識別子

優先名称: Copper(II) nitrate trihydrate
IUPAC: copper;dinitrate;trihydrate
現地名: 硝酸第２（３水）
英語名: Cupric nitrate trihydrate
分子式: CuH3NO4
分子量: 144.57

名称と別名

Copper(II) nitrate trihydrate10031-43-3Copper nitrate trihydrateCupric nitrate trihydrateGerharditeCopper dinitrate trihydratecopper;dinitrate;trihydrateCopper(2+) nitrate trihydrateMFCD00149671Nitric acid, copper(2+) salt, trihydrateCOPPER(II) NITRATE, TRIHYDRATE (1:2:3)066PG1506T

名称をさらに表示

二硝酸銅三水和物硝酸（II）三水和物硝酸銅(II)三水和物硝酸銅(II)三水和物,3N硝酸第２（３水）ビス（硝酸）銅（II）三水和物硝酸銅(II)三水和物(硝酸第二銅三水和物)硝酸銅(II)三水和物,3N(硝酸第二銅三水和物)硝酸銅(Ⅱ),3水和物硝酸銅(II)三水和物 PURISS. P.A.,99-104%硝酸銅(Ⅱ)三水和物硝酸銅(II)三水和物, 99.9%硝酸銅(II) 三水和物硝酸銅(II)三水和物 (99.999%-Cu) PURATREM硝酸銅(II)三水和物, 99.5%二硝酸銅(II)・三水和物COPPER (II) NITRATECOPPER(II) NITRATE 3-HYDRATECopper(Ⅱ)nitrateCUPRIC NITRATE 3H2OCopper(Ii)NitrateArcopper(2+) dinitrate

Nitric acid, copper(2+) salt, hydrate (2:1:3)UNII-066PG1506TMFCD02253001CuH6N2O9copper(II)nitrate trihydrateSCHEMBL208379DTXSID0051445AKOS015903801

データベース識別子

CAS: 10031-43-3
PubChem CID: 9837674
DTXSID: DTXSID0051445
UNII: 066PG1506T
EC Number: 600-060-3

物性

構造計算による物性

極性表面積: 129 Å²
水素結合供与体数: 3
水素結合受容体数: 9
回転可能結合数: 0
重原子数: 12
形式電荷: 0
複雑度: 18.8

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds

Physical DescriptionBlue deliquescent solid; [Merck Index] Dark blue hygroscopic crystals; [Sigma-Aldrich MSDS]

物理化学的性質

融点: 114 °C · 114 °C
沸点: 170 °C · 170°C
比重(密度): 2 · 2,32 g/cm3
貯蔵温度: 5 °C · Store at +5°C to +30°C.
溶解性: 2670 g/リットル · 2670g/リットル
外見: 微粉
比重: 2.32 · 2.32
色: クリーム～ブラウン
PH: 3 · 3-4 (50g/l, H2O, 20℃)
水溶解度: 溶ける
安定性: 安定。強力な酸化剤 - 可燃物に引火する可能性があります。湿気に敏感。酸無水物、アンモニア、アミド、シアン化物とは混和しません。
InChI: InChI=1S/Cu.HNO3.H2O/c;2-1(3)4;/h;(H,2,3,4);1H2
InChIKey: VVHXYVGAMODMHK-UHFFFAOYSA-N
SMILES: N(O)(=O)=O.[Cu].O
CAS データベース: 10031 · 10031-43-3(CAS DataBase Reference)
NISTの化学物質情報: Copper dinitrate(10031-43-3)

化学的性質

化学的特性Hygroscopic blue crystal with an order of nitric a

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 1.1% (5 of 448) of reports.

Danger

H272 (78.1%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P321, P330, P332+P317, P337+P317, P362+P364, P363, P370+P378, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 448 reports by companies from 20 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

危険有害性情報

Regulatory InformationChemical: Nitric acid, copper(2+) salt, trihydrate

Hazards Summary · 1 件

An oxidizer that may intensify fire; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion and skin absorption; Targets the blood, liver, kidney, CNS, and vascular system; [Sigma-Aldrich MSDS] See Copper(II) nitrate.

Hazard Classes and Categories · 2 件

Ox. Sol. 2 (78.1%)

Acute toxicity (Oral) - Category 4

安全と保護具

Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]

Threshold Limit Values (TLV)1.0 [mg/m3], as Cu

Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu

Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

F: 3
wgk: 2
rtecs: GL7875000
ridadr: UN 3085 5.1/PG 2
毒性: LD50 orally in Rabbit: 940 mg/kg
PRTR法: 1-272
hs_code: 28342930
risk_code: 8-22-34-36/38-50/53-41-38
安衛法: 57,57-2
消防法: 危険物第1類
hazard_code: O,C,Xn,N
safety_code: 17-26-36/37/39-45-37/39-61-60-39
hazard_class: 5.1
packing_group: II
毒劇物取締法: III
Hazard Classifications: Aquatic Acute 1Aquatic Chronic 2Eye Dam. 1Ox. Sol. 2Skin Corr. 1B
ストレージクラス: 5.1B - Oxidizing hazardous materials
危険度評価（NFPA 704基準/消防庁データ）: 人的[青]=1 火災[赤]=0 反応[黄]=1

化学と産業

用途と製造

Uses · 3 件

Used in light-sensitive paper, ceramics, textile dyeing (mordant), nickel-plating baths, aluminum brighteners, wood-preservatives, fungicides, herbicides, pyrotechnic compositions, and catalysts; Also used as a reagent for burnishing iron, giving a black antique finish to copper, coloring zinc brown, and a nitrating agent for aromatic organosilicon compounds; [Merck Index]

Aluminum Producing [Category: Industry]

Ceramics making [Category: Hobbies]

応用分野 · 4 件

用途分析におけるCuイオンの供給源、触媒、メッキ材料。

使用Analytical Reagent

使用Copper(II) nitrate trihydrate may be used in the preparation of the following mononuclear copper(II) complexes (phen = 1,10-phenanthroline, dpq = dipyrido[3,2-d:2′,3′-f]quinoxaline and dppz = dipyrido[3,2-a:2′,3′-c]phenazine):[Cu(dpq)(NO3)2][Cu(dpq)(NO3)(H2O)2](NO3)[Cu(dpq)(NO3)2(H2O)2]·2H2O[Cu(dppz)(NO3)2(H2O)]·H2O

一般的な説明Copper(II) nitrate trihydrate is a hydrated copper salt. It participates as catalyst in the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates.

調製方法 · 1 件

純化方法Crystallise it from weak aqueous HNO3 (0.5mL/g) by cooling from room temperature. The anhydrous salt can be prepared by dissolving copper metal in a 1:1 mixture of liquid NO2 and ethyl acetate and purified by sublimation [Evans et al. J Chem Soc, Faraday Trans 1 75 1023 1979]. The hexahydrate dehydrates to the trihydrate at 26o, and the anhydrous salt sublimes between 150 and 225o, but melts at 255-256o and is deliquescent.

上流・下流製品情報

上流原料

下流製品

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化合物ノート

読み込み中…

硝酸第２（３水）

基本情報

概要