N-tert-butylhydroxylamine → alpha-(2,4,6-Triethoxyphenyl)-N-tert-butylnitrone

反応式

[CH2:1]([O:3][C:4]1[CH:11]=[C:10]([O:12][CH2:13][CH3:14])[CH:9]=[C:8]([O:15][CH2:16][CH3:17])[C:5]=1[CH:6]=O)[CH3:2].[C:18]([NH:22][OH:23])([CH3:21])([CH3:20])[CH3:19]>>[CH2:1]([O:3][C:4]1[CH:11]=[C:10]([O:12][CH2:13][CH3:14])[CH:9]=[C:8]([O:15][CH2:16][CH3:17])[C:5]=1[CH:6]=[N+:22]([C:18]([CH3:21])([CH3:20])[CH3:19])[O-:23])[CH3:2]

参加物

反応物 2

HCID 98586N-tert-butylhydroxylamine

HCID 2897412,4,6-Triethoxybenzaldehyde

生成物 1

HCID 86587901alpha-(2,4,6-Triethoxyphenyl)-N-tert-butylnitrone

実験手順

The title compound was prepared according to the procedure described in Example 11 using 2,4,6-triethoxybenzaldehyde and N-tert-butylhydroxylamine. The title compound was isolated in 92.3% yield as a solid, m.p. 109.1° C.

後処理

customThe title compound was prepared

出典と根拠

ORDレコード: ord-3fb14f1eac77423e9f95db08d8a07d54
出典データセット: uspto-grants-2000_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06046232

反応ノート

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