Methane → 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

HRID 1004749

反応式

HRID 1004749 の反応式
[C:1]([O:4][CH:5]=[CH:6][CH:7]=C)(=[O:3])[CH3:2].[C:9]1([SiH:15]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C>C1(C)C=CC=CC=1>[C:22]1([Si:15]([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:7]=[CH:6][CH2:5][O:4][C:1](=[O:3])[CH3:2])[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1

参加物

5

反応物 3

HCID 297MethaneHCID 151951,3-Butadienyl acetateHCID 69922Triphenylsilane

生成物 1

HCID 538005221,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A solution of 1-acetoxy-1,3-butadiene (0.1 mol), triphenylsilane (0.1 mol), and Rh2Cl2 (CO)4 (194.5 mg, 0.625 mol) in 100 mL of toluene was stirred at room temperature under argon for 3 days. The reaction mixture is treated with decolorizing charcoal, and the mixture boiled briefly. After cooling, the reaction mixture is filtered through Celite. Concentration of the solution will afford the title compound.

後処理

  1. temperatureAfter cooling
  2. filtrationthe reaction mixture is filtered through Celite

出典と根拠

ORDレコード
ord-4baec51b142348798f2b34373f01253c
出典データセット
uspto-grants-2000_04
特許番号
US06051699

関連ノート

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