Water → 1,2-Cyclohexanediol, 4-ethenyl-

HRID 1007626

反応式

HRID 1007626 の反応式
[CH2:1]=[CH:2][CH:3]1[CH2:8][CH:7]2[O:9][CH:6]2[CH2:5][CH2:4]1.O.S(=O)(=O)(O)[OH:12]>CC(C)=O>[OH:9][CH:6]1[CH2:5][CH2:4][CH:3]([CH:2]=[CH2:1])[CH2:8][CH:7]1[OH:12]

参加物

5

反応物 3

HCID 962WaterHCID 1118Sulfuric AcidHCID 78327-Oxabicyclo(4.1.0)heptane, 3-ethenyl-

生成物 1

HCID 1473931,2-Cyclohexanediol, 4-ethenyl-

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

Into a two-neck flask (100 ml) were fed 15.9 g (128 mmol) of 4-vinylcyclohexene-1,2-epoxide, 40 ml of water, 20 ml of acetone, and 40 μl of sulfuric acid, and the reaction mixture was refluxed at 75° C. for 4 hours. After complete reaction, an object compound was extracted with each 60 ml of diethylether four times, and was washed with saturated salt solution, and then was dried with sodium sulfate. The solvent was evaporated to obtain 1,2-dihydroxy-4-vinylcyclohexane.

後処理

  1. customInto a two-neck flask (100 ml) were fed
  2. customAfter complete reaction
  3. extractionan object compound was extracted with each 60 ml of diethylether four times
  4. washwas washed with saturated salt solution
  5. dry with materialwas dried with sodium sulfate
  6. customThe solvent was evaporated

出典と根拠

ORDレコード
ord-d9c81395887b4a68a55f9994d3fb913c
出典データセット
uspto-grants-2004_09
特許番号
US06794528B2

関連ノート

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