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HRID 10131作成日:2026年10月25日

(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal → (3R,5S)-6-benzoyloxy-3,5-dihydroxyhexanoic tert-butyl ester

https://huagongshe.com/reaction/10131

反応式

関与物質

役割名称HCID仕込み量
反応物(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 107526—
反応物(S)-6-benzoyloxy-3-oxo-5-hydroxyhexanoic acid tert-butylesterHCID 15099849—
溶媒PhosphateHCID 1061—
生成物(3R,5S)-6-benzoyloxy-3,5-dihydroxyhexanoic tert-butyl esterHCID 11484150—

反応手順

Using 5 ml of Medium C described hereinbefore, the microorganisms indicated in Table 4 were cultured in the same manner as in Example 11. From 5 ml of each culture, the cells were centrifugally harvested, suspended in 0.5 ml of 100 mM phosphate buffer (pH 6.5) containing 0.05% of (5S)-6-benzoyloxy-5-hydroxy-3-oxohexanoic tert-butyl ester and 8% of glucose, and the reaction was carried out in the same manner. The results are shown in Table 4.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US07094594B2
出典データセットuspto-grants-2006_08
ORD IDord-bf0fdec98e874af7be6a18c9a6110a97
出典メモuspto-grants-2006_08