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(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal → (3R,5S)-6-benzoyloxy-3,5-dihydroxyhexanoic tert-butyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| 反応物 | (S)-6-benzoyloxy-3-oxo-5-hydroxyhexanoic acid tert-butylester | HCID 15099849 | — |
| 溶媒 | Phosphate | HCID 1061 | — |
| 生成物 | (3R,5S)-6-benzoyloxy-3,5-dihydroxyhexanoic tert-butyl ester | HCID 11484150 | — |
反応手順
Using 5 ml of Medium C described hereinbefore, the microorganisms indicated in Table 4 were cultured in the same manner as in Example 11. From 5 ml of each culture, the cells were centrifugally harvested, suspended in 0.5 ml of 100 mM phosphate buffer (pH 6.5) containing 0.05% of (5S)-6-benzoyloxy-5-hydroxy-3-oxohexanoic tert-butyl ester and 8% of glucose, and the reaction was carried out in the same manner. The results are shown in Table 4.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07094594B2 |
| 出典データセット | uspto-grants-2006_08 |
| ORD ID | ord-bf0fdec98e874af7be6a18c9a6110a97 |
| 出典メモ | uspto-grants-2006_08 |