Hexane → HCID 178493398、化合物
反応式
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([NH:11][CH:12]=[C:13]2[C:18](=[O:19])OC(C)(C)OC2=O)[CH:6]=[C:7]([O:9][CH3:10])[CH:8]=1.CCCCCC>C1(OC2C=CC=CC=2)C=CC=CC=1>[CH3:10][O:9][C:7]1[CH:8]=[C:3]([O:2][CH3:1])[CH:4]=[C:5]2[C:6]=1[C:18]([OH:19])=[CH:13][CH:12]=[N:11]2参加物
4
実験手順
A solution of 5-((3,5-dimethoxyphenylamino)methylene)-2,2-dimethyl-1,3-dioxane-4,6-dione (9.23 g, 30.0 mmol) in diphenyl ether was heated at 200° C. for 20 min., then cooled down to RT. Hexane was added and the mixture was stirred at RT for 30 mins. The solvent was removed to furnish 5,7-dimethoxyquinolin-4-ol as a light brown solid, which was used for next step without further purification. MS Found m/z=[M+H]+. 206.2 Calc'd for C11H11NO3: 205.2.
後処理
- customThe solvent was removed
出典と根拠
- ORDレコード
- ord-6526ff39e9a446bdb0a3bfe746124557
- 出典データセット
- uspto-grants-2011_07
- 特許番号
- US07981891B2
反応ノート
読み込み中…