3-(Trifluoromethyl)phenol → HCID 178418715、化合物

HRID 10155

反応式

HRID 10155 の反応式
[CH:1]1([Zr:6](C)C)[CH:5]=[CH:4][CH:3]=[CH:2]1.[F:9][C:10]([F:19])([F:18])[C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([OH:17])[CH:12]=1>C1(C)C=CC=CC=1>[CH:1]1([Zr:6]([O:17][C:13]2[CH:14]=[CH:15][CH:16]=[C:11]([C:10]([F:9])([F:18])[F:19])[CH:12]=2)[O:17][C:13]2[CH:14]=[CH:15][CH:16]=[C:11]([C:10]([F:18])([F:19])[F:9])[CH:12]=2)[CH:5]=[CH:4][CH:3]=[CH:2]1

参加物

4

反応物 2

HCID 73763-(Trifluoromethyl)phenolHCID 178418892HCID 178418892、化合物

生成物 1

HCID 178418715HCID 178418715、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒3 回

実験手順

To a 50 ml Schlenk flask containing 138.7 mg (0.5 mmole) of (1-methylboratabenzene) (cyclopentadienyl) dimethyl zirconium [intermediate product of 1st Step] in 15 ml toluene and at 0° C., 162.1 mg (1 mmole) of Trifluoro-m-Cresol in 10 ml toluene is added slowly under stirring. After warming up to room temperature and stirring one hour at room temperature, toluene of the reaction mixture is moved by vacuum. The desired product (1-methylboratabenzene) (cyclopentadienyl) bis(3-trifluoromethylphenoxy) zirconium can be obtained from the residue of vacuum distillation.

後処理

  1. stirringstirring one hour at room temperature

出典と根拠

ORDレコード
ord-6cea0494348b410e84f555c127ac38a6
出典データセット
uspto-grants-2006_08
特許番号
US07094723B2

関連ノート

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