関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1,1,1-Trichloro-2,2,2-trifluoroethane | HCID 9635 | — |
| 反応物 | Propane, 2-(ethenyloxy)-2-methyl- | HCID 70220 | — |
| 触媒 | Mercury | HCID 23931 | — |
| 生成物 | HCID 54430105 | HCID 54430105 | 60% |
反応手順
A mixture of 1,1,1-trifluoro-2,2,2-trichloroethane and tert-butylvinyl ether in a 3:1 molar ratio is introduced to a jacketed photochemical reaction vessel. The mixture is irradiated using a medium-pressure mercury UV lamp so as to maintain the temperature of the mixture at about 35-45° C. for about 2 hours. The resultant reaction mixture is concentrated to remove volatiles and distilled to produce 3-chloro-4,4,4-trifluorobut-2-enal in a 60% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06476279B2 |
|---|
| 出典データセット | uspto-grants-2002_11 |
|---|
| ORD ID | ord-6ba90947a37f4507b6f63d1f42967f69 |
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| 出典メモ | uspto-grants-2002_11 |
|---|
