3-Hydroxy-6-phenoxyhexanoic acid → 8-phenoxyoctanoic Acid

HRID 1017977ノート

反応式

HRID 1017977 の反応式
OC(COC1C=CC=CC=1)CC(O)=O.OC(CCCOC1C=CC=CC=1)CC(O)=O.O[CH:32]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][O:42][C:43]1[CH:48]=[CH:47][CH:46]=[CH:45][CH:44]=1)[CH2:33][C:34]([OH:36])=[O:35]>>[O:42]([CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:32][CH2:33][C:34]([OH:36])=[O:35])[C:43]1[CH:48]=[CH:47][CH:46]=[CH:45][CH:44]=1

参加物

4

反応物 3

HCID 220240423-Hydroxy-6-phenoxyhexanoic acidHCID 220240433-Hydroxy-8-phenoxyoctanoic acidHCID 22024050HCID 22024050、化合物

生成物 1

HCID 102203288-phenoxyoctanoic Acid

実験手順

Also, in Macromolecules, 29, 3432-3435 (1996), it is reported that using Pseudomonas oleovorans, PHA containing 3-hydroxy-4-phenoxybutyric acid and 3-hydroxy-6-phenoxyhexanoic acid as units is produced from 6-phenoxyhexanoic acid, PHA containing 3-hydroxy-4-phenoxybutyric acid, 3-hydroxy-6-phenoxyhexanoic acid and 3-hydroxy-8-phenoxyoctanoic acid as units is produced from 8-phenoxyoctanoic acid, and PHA containing 3-hydroxy-5-phenoxyvaleric acid and 3-hydroxy-7-phenoxyheptanoic acid as units is produced from 11-phenoxyundecanoic acid. Yields of polymers in this report are extracted and are shown in the following.

出典と根拠

ORDレコード
ord-e916ef9d964f4847ae6e9ea7ee1623da
出典データセット
uspto-grants-2002_11
特許番号
US06479621B2

反応ノート

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