Sorbitol → D-Iditol

HRID 1019424

反応式

HRID 1019424 の反応式
[OH:1][CH2:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[CH2:13]([OH:24])[C@H:14]([C@H:16]([C@@H:18]([C@@H:20]([CH2:22][OH:23])[OH:21])[OH:19])[OH:17])[OH:15]>>[CH2:11]([OH:12])[C@H:9]([C@@H:7]([C@H:5]([C@@H:3]([CH2:2][OH:1])[OH:4])[OH:6])[OH:8])[OH:10].[O:23]=[CH:22][C@@H:20]([C@H:18]([C@H:16]([C@@H:14]([CH2:13][OH:24])[OH:15])[OH:17])[OH:19])[OH:21]

参加物

4

反応物 2

HCID 5780Sorbitol2 回HCID 6251Mannitol

生成物 2

HCID 90540D-IditolHCID 3037556(2R,3S,4S,5R)-2,3,4,5,6-pentahydroxyhexanal

実験手順

Both glucose and fructose can be hydrogenated into the sugar alcohol or corresponding hexitol. The hexitol produced by the hydrogenation of glucose is sorbitol, while the hydrogenation of fructose leads to a mixture of sorbitol and mannitol. Iditol is produced by the hydrogenation of galactose, an hexose.

出典と根拠

ORDレコード
ord-df44b4908ad746eea4f396f8806ee6a3
出典データセット
uspto-grants-2014_05
特許番号
US08715372B2

関連ノート

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