HCID 59355188、化合物 → HCID 59355176、化合物
反応式
[CH3:1][N:2]([CH3:13])[CH2:3][CH2:4][NH:5][CH2:6][C:7]([CH3:12])([N+:9]([O-])=O)[CH3:8]>CO.[Ni].O>[CH3:13][N:2]([CH3:1])[CH2:3][CH2:4][NH:5][CH2:6][C:7]([CH3:8])([NH2:9])[CH3:12]参加物
5
実験手順
To a solution of N1,N1-dimethyl-N2-(2-methyl-2-nitropropyl)ethane-1,2-diamine (23.2 mmol) in MeOH (20 ml) was added a slurry of Raney Nickel in H2O (1 ml). The vessel was pressurized with H2 (500 psi) and the suspension stirred for 24 h. The mixture was filtered through Celite, then 0.45 um PTFE, and concentrated in vacuo. ESI/APCI (pos) expected for C8H21N3: 159.17. Found: 160 (MH+).
後処理
- filtrationThe mixture was filtered through Celite
- concentration0.45 um PTFE, and concentrated in vacuo
出典と根拠
- ORDレコード
- ord-05cc1d1f75f842389e569eb09d38a6cb
- 出典データセット
- uspto-grants-2014_05
- 特許番号
- US08722715B2
反応ノート
読み込み中…