Dichloromethane → 3-(3-bromophenyl)-3-[4-(7-[2-(trimethylsilyl)ethoxy]methyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl]propanal

反応式

[Br:11][c:12]1[cH:13][c:14]([CH:18]([CH2:19][C:20](=[O:21])[O:22][CH2:23][CH3:24])[n:25]2[n:26][cH:27][c:28](-[c:30]3[c:31]4[c:32]([n:33][cH:34][n:35]3)[n:36]([CH2:39][O:40][CH2:41][CH2:42][Si:43]([CH3:44])([CH3:45])[CH3:46])[cH:37][cH:38]4)[cH:29]2)[cH:15][cH:16][cH:17]1.[CH2:2]([Al+:3][CH2:4][CH:5]([CH3:6])[CH3:7])[CH:8]([CH3:9])[CH3:10].[CH3:50][CH2:51][CH2:52][CH2:53][CH2:54][CH3:55].[Cl:47][CH2:48][Cl:49].[H-:1]>>[Br:11][c:12]1[cH:13][c:14]([CH:18]([CH2:19][CH:20]=[O:21])[n:25]2[n:26][cH:27][c:28](-[c:30]3[c:31]4[c:32]([n:33][cH:34][n:35]3)[n:36]([CH2:39][O:40][CH2:41][CH2:42][Si:43]([CH3:44])([CH3:45])[CH3:46])[cH:37][cH:38]4)[cH:29]2)[cH:15][cH:16][cH:17]1