Methyl fluorosulfate → 3-(4-Methoxybenzylthio)-1-methylquinuclidinium fluorosulfonate

HRID 1030174

反応式

HRID 1030174 の反応式
[CH3:1][O:2][C:3]1[CH:18]=[CH:17][C:6]([CH2:7][S:8][CH:9]2[CH:14]3[CH2:15][CH2:16][N:11]([CH2:12][CH2:13]3)[CH2:10]2)=[CH:5][CH:4]=1.[F:19][S:20]([O:23][CH3:24])(=[O:22])=[O:21]>C(Cl)Cl>[F:19][S:20]([O-:23])(=[O:22])=[O:21].[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([CH2:7][S:8][CH:9]2[CH:14]3[CH2:13][CH2:12][N+:11]([CH3:24])([CH2:16][CH2:15]3)[CH2:10]2)=[CH:17][CH:18]=1

参加物

4

反応物 2

HCID 9870Methyl fluorosulfateHCID 197972653-(4-Methoxybenzylthio)quinuclidine

生成物 1

HCID 197972503-(4-Methoxybenzylthio)-1-methylquinuclidinium fluorosulfonate

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

The procedure described in preparation 6-(3) was repeated, but using 756 mg of 3-(4-methoxybenzylthio) quinuclidine and 271 μl of methyl fluorosulfonate in the presence of 5 ml of methylene chloride, to afford 1.078 g of the title compound as an oil.

後処理

  1. customThe procedure described in preparation 6-(3)

出典と根拠

ORDレコード
ord-d6f53c977c6a4da88b5af247b46a3d95
出典データセット
uspto-grants-1992_04
特許番号
US05104867

関連ノート

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