2-phenyl-2H-benzo[d][1,2,3]triazole 1-oxide → 2H-Benzotriazole, 2-phenyl-

HRID 1030310ノート

反応式

HRID 1030310 の反応式
[C:1]1([N:7]2[N+:11]([O-])=[C:10]3[CH:13]=[CH:14][CH:15]=[CH:16][C:9]3=[N:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H][H]>>[C:1]1([N:7]2[N:8]=[C:9]3[CH:16]=[CH:15][CH:14]=[CH:13][C:10]3=[N:11]2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

参加物

3

反応物 2

HCID 45667942-phenyl-2H-benzo[d][1,2,3]triazole 1-oxideHCID 178418361HCID 178418361、化合物2 回

生成物 1

HCID 1540962H-Benzotriazole, 2-phenyl-

実験手順

A 2-phenylbenzotriazole-N-oxide which is the chosen starting material is dissolved in a solvent contained in a reaction vessel into which a hydrogenation catalyst and a basic substance are then placed. After the air in the reaction vessel has been replaced by hydrogen, a given amount of hydrogen is charged into the reaction vessel, and the reaction is then allowed to proceed under atmospheric pressure or a given pressure at a temperature of room temperature to 170° C. under agitation. After the reaction has been completed, the catalyst is filtered off, the solvent layer is washed with water, and the solvent is distilled off. The crude product is then purified by recrystallization to obtain the corresponding 2-phenylbenzotriazole as a pure product.

後処理

  1. dissolutionis dissolved in a solvent
  2. customcontained in a reaction vessel into which
  3. customat a temperature of room temperature to 170° C.
  4. filtrationthe catalyst is filtered off
  5. washthe solvent layer is washed with water
  6. distillationthe solvent is distilled off
  7. customThe crude product is then purified by recrystallization

出典と根拠

ORDレコード
ord-460808956332473687a7318bbcc20239
出典データセット
uspto-grants-1992_04
特許番号
US05104992

反応ノート

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