Hydrochloric Acid → 2-Acetyl-6-methoxynaphthalene
反応式
[Cl-].[Al+3].[Cl-].[Cl-].[C:5]([C:8]1[CH:17]=[CH:16][C:15]2[C:10](=[CH:11][CH:12]=[C:13]([O:19][CH3:20])[C:14]=2Br)[CH:9]=1)(=[O:7])[CH3:6].Cl>C1(C)C=CC=CC=1>[C:5]([C:8]1[CH:17]=[CH:16][C:15]2[C:10](=[CH:11][CH:12]=[C:13]([O:19][CH3:20])[CH:14]=2)[CH:9]=1)(=[O:7])[CH3:6]参加物
5
実験手順
8.2 Grams of anhydrous aluminum chloride and 59 ml of toluene are added to the solution of 2-acetyl-5-bromo-6-methoxynaphthalene obtained in example 1, keeping the temperature at -10° C. The reaction mixture is kept under stirring at room temperature for 20 hours and then it is slowly poured into a mixture made by 200 g of crushed ice and by 75 ml of a 35% (w/v) aqueous solution of hydrochloric acid.
後処理
- customat -10° C
- additionit is slowly poured into a mixture
出典と根拠
- ORDレコード
- ord-b0c0a35a8561482ba650ad8cca7fc128
- 出典データセット
- uspto-grants-1992_04
- 特許番号
- US05107013
反応ノート
読み込み中…