Water → HCID 15057055、化合物
反応式
[C:1]1([OH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([O-])([O-])=O.[K+].[K+].Cl[C:15]1[CH:20]=[CH:19][N:18]=[CH:17][C:16]=1[N+:21]([O-:23])=[O:22].O>CN(C=O)C>[N+:21]([C:16]1[CH:17]=[N:18][CH:19]=[CH:20][C:15]=1[O:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)([O-:23])=[O:22]参加物
6
実験手順
To phenol (6.5 g) in 20 ml DMF at room temperature was added K2CO3 (20 g) and this mixture stirred for 15 minutes at room temperature. Then 4-chloro-3-nitropyridine (10.0 g) in 60 ml DMF was added dropwise and the mixture stirred for two hours at ambient temperature. The mixture was poured into water and extracted with ethyl acetate. The organic layer was washed with water and dried (sat. NaCl, anhy. MgSO4).
後処理
- stirringthe mixture stirred for two hours at ambient temperature
- extractionextracted with ethyl acetate
- washThe organic layer was washed with water
- dry with materialdried (sat. NaCl
出典と根拠
- ORDレコード
- ord-17c964ed95c141f78522f65fdda6c718
- 出典データセット
- uspto-grants-1990_09
- 特許番号
- US04959377
反応ノート
読み込み中…