関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 9,10-Dihydroanthracene | HCID 11940 | — |
| 反応物 | Tetracyano-1,4-benzoquinone | HCID 10910733 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | Anthracene | HCID 8418 | — |
| 生成物 | Tetracyano-1,4-benzoquinone | HCID 10910733 | — |
反応手順
A solution of 9,10-dihydroanthracene (35 mg; 0.192 mmol) dissolved in 1 mL dry acetonitrile was reacted with tetracyano-1,4-benzoquinone (40 mg; 0.192 mmol) also dissolved in 1 mL dry acetonitrile. After reducing the volume in half and cooling to -20° C. crystals precipitated and were collected. The infrared spectra of the precipitate was identical to that obtained from a mixture of authentic anthracene and tetracyano-1,4-hydroquinone (ν(C≡N)=2239 and 2263 cm-1) verifying that tetracyano-1,4-benzoquinone dehydrogenates 9,10-dihydroanthracene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05310957 |
|---|
| 出典データセット | uspto-grants-1994_05 |
|---|
| ORD ID | ord-066e79c4e71f45b3bffeac34eb7cd748 |
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| 出典メモ | uspto-grants-1994_05 |
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