Hydrochloric Acid → Methyldiisopropylchlorosilane

HRID 1033912ノート

反応式

HRID 1033912 の反応式
[ClH:1].[CH3:2][SiH:3]([CH:7]([CH3:9])[CH3:8])[CH:4]([CH3:6])[CH3:5]>>[CH3:2][Si:3]([CH:7]([CH3:9])[CH3:8])([CH:4]([CH3:6])[CH3:5])[Cl:1]

参加物

3

反応物 2

HCID 313Hydrochloric Acid3 回HCID 101621268Diisopropyl(methyl)silane

生成物 1

HCID 6421633Methyldiisopropylchlorosilane

反応条件

温度
100 °C

実験手順

A thermometer, hydrogen chloride gas inlet tube, and reflux condenser were fitted to a stirrer-equipped 200 mL four-neck flask, and 100 g methyldiisopropylsilane was then introduced into the flask. This was followed by the addition of 0.01 g platinum/divinyltetramethyldisiloxane complex and heating to 100° C. Hydrogen chloride gas was then introduced into the mixture. The introduction of hydrogen chloride gas was suspended after 4 hours. Distillation at ambient pressure yielded 122 g methyldiisopropylchlorosilane (purity≥99%, bp=146° C.). The methyldiisopropylchlorosilane yield was 97%.

後処理

  1. customwere fitted to a stirrer-equipped 200 mL four-neck flask
  2. additionThis was followed by the addition of 0.01 g platinum/divinyltetramethyldisiloxane complex
  3. distillationDistillation at ambient pressure

出典と根拠

ORDレコード
ord-7b8adb2b15ea4227ace872254c168764
出典データセット
uspto-grants-1994_05
特許番号
US05312949

反応ノート

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