HCID 178435533、化合物 → HCID 178500160、化合物
反応式
[C:1]([C@H:5]1[CH2:10][CH2:9][C@H:8]([O:11][C:12]2[CH:13]=[C:14]3[C:19](=[CH:20][CH:21]=2)[CH:18]=[C:17]([C:22]([N+:30]([O-:32])=[O:31])([CH3:29])[CH2:23][CH2:24][C:25]([O:27][CH3:28])=[O:26])[CH:16]=[CH:15]3)[CH2:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2].C([C@H]1CC[C@H](OC2C=CC3C(=CC=C(C([N+]([O-])=O)C)C=3)C=2[C:59]([F:62])([F:61])[F:60])CC1)(C)(C)C>>[C:1]([C@H:5]1[CH2:6][CH2:7][C@H:8]([O:11][C:12]2[C:13]([C:59]([F:62])([F:61])[F:60])=[C:14]3[C:19](=[CH:20][CH:21]=2)[CH:18]=[C:17]([C:22]([N+:30]([O-:32])=[O:31])([CH3:29])[CH2:23][CH2:24][C:25]([O:27][CH3:28])=[O:26])[CH:16]=[CH:15]3)[CH2:9][CH2:10]1)([CH3:4])([CH3:2])[CH3:3]参加物
3
実験手順
Methyl 4-(6-(trans-4-tert-butylcyclohexyloxy)-5-(trifluoromethyl)naphthalen-2-yl)-4-nitropentanoate was synthesized as per methyl 4-(6-(trans-4-tert-butylcyclohexyloxy)naphthalen-2-yl)-4-nitropentanoate (Example 205) in 62% yield using 2-(trans-4-tert-butylcyclohexyloxy)-6-(1-nitroethyl)-1-(trifluoromethyl)naphthalene as starting material.
出典と根拠
- ORDレコード
- ord-b62b0f896a494eefb24a951b5306ee1b
- 出典データセット
- uspto-grants-2013_10