Butyl bromide → 1-Methyl-1-propylpyrrolidinium bromide
反応式
[CH3:1][N:2]1C[CH2:5][CH2:4][CH2:3]1.[Br:7][CH2:8][CH2:9][CH2:10][CH3:11].[F-].[K+]>>[Br-:7].[CH2:3]([N+:2]1([CH3:1])[CH2:11][CH2:10][CH2:9][CH2:8]1)[CH2:4][CH3:5]参加物
4
実験手順
Propylmethylpyrrolidinium bromide was prepared by Menshutkin reaction of N-methylpyrrolidine with 1-bromobutane. 21.5 g of the adduct formed by the IB-4 complex with KF were added to 20.8 g of [C4H8N(CH3)C3H7]Br in 100 ml of acetone. The suspension was stirred by means of a magnetic stirrer for 48 hours. The KBr formed during the reaction was eliminated by filtration and the precipitate was washed with two portions of 20 ml of acetone. The solvent was eliminated and a viscous liquid was recovered, corresponding to the formula:
出典と根拠
- ORDレコード
- ord-65c39467957d4e25b17113ef354bf67d
- 出典データセット
- uspto-grants-2013_10
- 特許番号
- US08563761B2
反応ノート
読み込み中…