Diethylamine → (2,2-Diethoxyethyl)diethylamine
反応式
Br[CH2:2][CH:3]([O:7][CH2:8][CH3:9])[O:4][CH2:5][CH3:6].[CH2:10]([NH:12][CH2:13][CH3:14])[CH3:11]>CC(C)=O>[CH2:5]([O:4][CH:3]([O:7][CH2:8][CH3:9])[CH2:2][N:12]([CH2:13][CH3:14])[CH2:10][CH3:11])[CH3:6]参加物
4
実験手順
2-bromo-1,1-diethoxyethane (10 g, 0.051 mol), diethylamine (11 g, 0.15 mol) and KI (8.5 g, 0.051 mol) were added in 100 mL acetone, and stirred for overnight at 40 degree. The resulting solution was filtered, concentrated and purified with silica gel column to give 2,2-diethoxy-N,N-diethylethanamine as brown oil 2.0 g (20.8% yield).
後処理
- filtrationThe resulting solution was filtered
- concentrationconcentrated
- custompurified with silica gel column
出典と根拠
- ORDレコード
- ord-1d05ce371e2c4dfb971a0a1523dbdd3f
- 出典データセット
- uspto-grants-2016_07
- 特許番号
- US09388170B2
反応ノート
読み込み中…