Methyl 1,2,3-benzothiadiazole-5-carboxylate → 1,2,3-Benzothiadiazole-5-carbaldehyde

HRID 1062698

反応式

HRID 1062698 の反応式
[S:1]1[C:5]2[CH:6]=[CH:7][C:8]([C:10](OC)=[O:11])=[CH:9][C:4]=2[N:3]=[N:2]1>[O-2].[Mn+2]>[S:1]1[C:5]2[CH:6]=[CH:7][C:8]([CH:10]=[O:11])=[CH:9][C:4]=2[N:3]=[N:2]1

参加物

3

反応物 1

HCID 2736813Methyl 1,2,3-benzothiadiazole-5-carboxylate

生成物 1

HCID 185046971,2,3-Benzothiadiazole-5-carbaldehyde

試薬・触媒・溶媒 1

HCID 160959Manganese oxide触媒

実験手順

This was prepared from methyl benzo[1,2,3]thiadiazole-5-carboxylate (0.291 g) by the method of Example 16c, (except that the alcohol was stirred with manganese (II) oxide overnight) and used without purification.

後処理

  1. customused without purification

出典と根拠

ORDレコード
ord-f06ec9fcdc574ca6a2a32bc09337fdf4
出典データセット
uspto-grants-2005_11
特許番号
US06962917B2

関連ノート

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