Ethyl sulfide → Diethylthioether Silver Nitrate

関与物質

反応手順

To a 100 ml round bottom flask was sequentially added 10 mmol (1.69 g) of silver nitrate and 20 ml of acetonitrile, followed by stirring at room temperature for 5 minutes. Next, 10 mmol (0.90 g, 1.08 ml) of diethylthioether was dropwise added to the flask by means of a syringe over 10 seconds and stirred at room temperature. After stirring for 30 minutes, the reaction mixture was warmed to 50° C. and further stirred for 30 minutes. Following cooling to room temperature, the reaction mixture was filtered through a microfilter and evaporated under vacuum to produce a pale ivory solid matter. 1H-NMR result in CD3CN is as follows: 1.34 (t, 7.36 Hz, 6H), 2.76(q, 7.36 Hz, 4H).

情報源と証拠