Potassium hexafluoroantimonate(1-) → Diphenyliodonium hexafluoroantimonate
反応式
Cl([O-])(=O)(=O)=O.[C:6]1([I+:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[F:19][Sb-:20]([F:25])([F:24])([F:23])([F:22])[F:21].[K+]>CO>[F:19][Sb-:20]([F:25])([F:24])([F:23])([F:22])[F:21].[C:13]1([I+:12][C:6]2[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1参加物
4
反応条件
- 温度
- 25 °C
実験手順
A mixture of 4 parts of diphenyliodonium perchlorate and 2.8 parts of potassium hexafluoroantimonate and 100 parts of methanol was stirred for 1 hour at 25° C. The resulting mixture was then filtered and the methanol solution evaporated to produce a solid having a melting point of 77°-87° C. Based on method of preparation there was obtained an 86.1% yield of diphenyliodonium hexafluoroantimonate.