Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

関与物質

役割	名称	HCID	仕込み量
反応物	Benzyl Chloride	HCID 7503	—
反応物	N,N,N',N'-Tetramethylethylenediamine	HCID 8037	—
反応物	Trichlorosilane	HCID 24811	—
生成物	Benzene, [(trichlorosilyl)methyl]-	HCID 69863	52%

反応手順

In the same apparatus and procedure as Example 1 above, 0.116 g (1.0 mmol) of N,N,N′,N′-tetramethylethylenediamine, 0.63 g (5.0 mmol) of benzyl chloride, and 3.41 g (25.2 mmol) of trichlorosilane were reacted at 200° C. for 7 hrs. The resulting mixture was distilled to give 0.57 g of benzyltrichlorosilane (yield; 52%).

情報源と証拠

DOI	10.6084/m9.figshare.5104873.v1
特許番号	US06251057B1
出典データセット	uspto-grants-2001_06
ORD ID	ord-816df09f590547248715d676c0189914
出典メモ	uspto-grants-2001_06