N,N,2-Trimethylaniline → p-Methoxybenzyltrichlorosilane

HRID 1068528ノート

反応式

HRID 1068528 の反応式
CN(C)C1C(C)=CC=CC=1.[CH3:11][O:12][C:13]1[CH:20]=[CH:19][C:16]([CH2:17]Cl)=[CH:15][CH:14]=1.[Cl:21][SiH:22]([Cl:24])[Cl:23]>>[CH3:11][O:12][C:13]1[CH:20]=[CH:19][C:16]([CH2:17][Si:22]([Cl:24])([Cl:23])[Cl:21])=[CH:15][CH:14]=1

参加物

4

反応物 3

HCID 11869N,N,2-TrimethylanilineHCID 24811TrichlorosilaneHCID 699934-Methyloxybenzyl chloride

生成物 1

HCID 11482253p-Methoxybenzyltrichlorosilane収率 11.3%

実験手順

In the same apparatus and procedure as Example 1 above, 0.06 g (0.45 mmol) of N,N-dimethyltoluidine, 0.7 g (4.5 mmol) of 4-methoxybenzyl chloride, and 3.05 g (22.5 mmol) of trichlorosilane were reacted at 200+ C. for 15 hrs. The resulting mixture was distilled to give 0.13 g of (4-methoxybenzyl)trichlorosilane (yield; 11%).

後処理

  1. distillationThe resulting mixture was distilled

出典と根拠

ORDレコード
ord-386dd98b71b5429bb4eb1c57d306cbbf
出典データセット
uspto-grants-2001_06
特許番号
US06251057B1

反応ノート

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