関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Sulfuryl chloride | HCID 24648 | — |
| 反応物 | Benzyl Phenyl Ether | HCID 70352 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 4-(Benzyloxy)benzene-1-sulfonyl chloride | HCID 4738385 | — |
反応手順
A 1.12 portion of anhydrous DMF is cooled to 0° C. and treated dropwise with 2.06 g of sulfuryl chloride. The resulting suspension is stirred for 30 min., then treated with 1.50 g of benzyl phenyl ether. The mixture is heated at 90° C. for 3 h, then cooled, extracted with brine and methylene chloride, and dried over MgSO4. Chormotography on silica gel (i-PrOH/hexanes) yields 4-benzyloxybenzenesulfonyl chloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05723490 |
|---|
| 出典データセット | uspto-grants-1998_03 |
|---|
| ORD ID | ord-7b357d5bf4334f0fb405475a558ece52 |
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| 出典メモ | uspto-grants-1998_03 |
|---|
