Tributylstannane → 1-(tributylstannyl)-1E-undecen-3-ol

HRID 1073646ノート

反応式

HRID 1073646 の反応式
[CH:1]#[C:2][CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([SnH:17]([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:18][CH2:19][CH2:20][CH3:21])[CH2:14][CH2:15][CH3:16]>>[CH2:22]([Sn:17]([CH2:13][CH2:14][CH2:15][CH3:16])([CH2:18][CH2:19][CH2:20][CH3:21])/[CH:1]=[CH:2]/[CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:23][CH2:24][CH3:25]

参加物

3

反応物 2

HCID 5948TributylstannaneHCID 2477661-Undecyn-3-ol

生成物 1

HCID 121582911-(tributylstannyl)-1E-undecen-3-ol

反応条件

温度
120 °C

実験手順

To 0.07 g (0.42 mmol) of the titled product of Example 7 is added 0.15 g (0.5 mmol) of tri-n-butyltin hydride and 20 mg of azoisobutyronitrile (AIBN). The reaction mixture was heated to 120° C. for 2 hours. Afterwards, it was cooled to room temperature and pumped at high vacuum overnight. The crude reaction mixture was then heated to 90° C. and maintained at high vacuum for 2 additional hours. Upon cooling to room temperature, the crude product was used as is.

後処理

  1. temperatureAfterwards, it was cooled to room temperature
  2. custompumped at high vacuum overnight
  3. customThe crude reaction mixture
  4. temperaturewas then heated to 90° C.
  5. temperaturemaintained at high vacuum for 2 additional hours
  6. temperatureUpon cooling to room temperature

出典と根拠

ORDレコード
ord-1c275844a8354614ab54f2b7bfa78c94
出典データセット
uspto-grants-1990_11
特許番号
US04970234

反応ノート

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