Triphenylphosphine → (3-Methylbut-2-enyl)triphenylphosphonium bromide

HRID 1073689

反応式

HRID 1073689 の反応式
[CH3:1][C:2]([CH3:6])=[CH:3][CH2:4][Br:5].[C:7]1([P:13]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>C1(C)C=CC=CC=1>[Br-:5].[CH3:1][C:2]([CH3:6])=[CH:3][CH2:4][P+:13]([C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[C:7]1[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=1

参加物

4

反応物 2

HCID 11776TriphenylphosphineHCID 700922-Butene, 1-bromo-3-methyl-

生成物 1

HCID 3083722(3-Methylbut-2-enyl)triphenylphosphonium bromide

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A mixture of 3,3-dimethylallyl bromide (50.0 g), triphenylphosphine (88.0 g) and dry toluene (500 ml) was stirred and heated at the reflux temperature for one hour, and then kept at the ambient temperature for 18 hours. The white precipitate of 3,3-dimethylall-yl triphenylphosphonium bromide (m.p. 242° C.) was collected by filtration, washed with diethyl ether and dried.

後処理

  1. temperatureheated at the reflux temperature for one hour
  2. filtrationThe white precipitate of 3,3-dimethylall-yl triphenylphosphonium bromide (m.p. 242° C.) was collected by filtration
  3. washwashed with diethyl ether
  4. customdried

出典と根拠

ORDレコード
ord-3f4384b5fe984591a934eb49c1c3c893
出典データセット
uspto-grants-1990_11
特許番号
US04970330

関連ノート

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