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Ethyl bromoacetate → Ethyl 2-(4-methoxyphenyl)sulfanylacetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethyl bromoacetate | HCID 7748 | — |
| 反応物 | 4-Methoxybenzenethiol | HCID 12765 | — |
| 反応物 | Acetic acid, (phenylthio)-, ethyl ester | HCID 97312 | — |
| 反応物 | Sodium ethoxide | HCID 2723922 | — |
| 生成物 | Ethyl 2-(4-methoxyphenyl)sulfanylacetate | HCID 1482371 | — |
反応手順
The procedure is as in Example 2 for the preparation of ethyl (phenylthio)acetate starting with ethyl bromoacetate (11.7 g), a 2M ethanolic solution of sodium ethylate (35 cc) and 4-methoxythiophenol (10 g). Ethyl (4-methoxyphenylthio)acetate (13.6 g) is thereby obtained, and is used in the crude state in the subsequent syntheses.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04971979 |
| 出典データセット | uspto-grants-1990_11 |
| ORD ID | ord-932e9b83c0e048d8b371dc79eca353da |
| 出典メモ | uspto-grants-1990_11 |