Hydrochloric Acid → HCID 22155954、化合物

HRID 1074199ノート

反応式

HRID 1074199 の反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][C:11]2[NH:12][CH:13]=[CH:14][N:15]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2].[ClH:16]>CO.C(O)C>[ClH:16].[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][C:11]2[NH:15][CH:14]=[CH:13][N:12]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2]

参加物

5

反応物 2

HCID 313Hydrochloric AcidHCID 150774982-[(4-Nitrophenyl)thio]-1H-imidazole

生成物 1

HCID 22155954HCID 22155954、化合物

試薬・触媒・溶媒 2

HCID 702Ethanol溶媒HCID 887Methanol溶媒

実験手順

The product from Example 26 was dissolved in methanol and treated with an excess of hydrogen chloride in ethyl alcohol. The mixture was concentrated and the residue triturated with ether and filtered. The solid was recrystallized from methanol to give the product as colorless prisms, mp 235°-240° C. (sealed tube).

後処理

  1. concentrationThe mixture was concentrated
  2. customthe residue triturated with ether
  3. filtrationfiltered
  4. customThe solid was recrystallized from methanol
  5. customto give

出典と根拠

ORDレコード
ord-02409625d3164c6985dedd1c1d7c52dc
出典データセット
uspto-grants-1990_11
特許番号
US04973599

反応ノート

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