Ethylenediamine → N-dodecylethylenediamine

HRID 1075723

反応式

HRID 1075723 の反応式
[CH2:1]([NH2:4])[CH2:2][NH2:3].[CH2:5](Cl)[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>C(O)C>[CH2:16]([NH:3][CH2:2][CH2:1][NH2:4])[CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH3:5]

参加物

4

反応物 2

HCID 3301EthylenediamineHCID 81921-Chlorododecane

生成物 1

HCID 10561362N-dodecylethylenediamine

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

N-propylol-N'-lauryl ethylenediamine is prepared by dissolving 2 kmol ethylenediamine in 500 liters absolute ethanol and then, while constantly stirring, 2 kmol laurylchloride is added while the temperature is maintained not to exceed 100°C and then the reaction mixture is held for 1.5 hours at that temperature. N'-lauryl-ethylenediamine is formed. Subsequently the reaction mixture is cooled to 30°C, the chloride is precipitated with ammonia and the precipitate is filtered off. The pH value of the pure solution is adjusted to 8.5 and 2 kmol propionaldehyde ia added. The temperature is maintained at 40°C during a subsequent 3 hour period while stirring. Then the alcohol is driven off under vacuum and the unreacted products are washed out with water. The end product has a molecular weight of about 300 and the formula ##EQU12##

後処理

  1. temperatureis maintained not
  2. customto exceed 100°C

出典と根拠

ORDレコード
ord-3a72e44b851347bc8a1e6399072ba6af
出典データセット
uspto-grants-1976_05
特許番号
US03954436

関連ノート

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