Cyclohexanone → Cyclohexene-1-yl acetate

HRID 1076087

反応式

HRID 1076087 の反応式
C1(=O)CCCCC1.[H][H].[C:10]([O:13][CH:14]1[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]1)(=[O:12])[CH3:11]>C(O)(=O)C>[C:10]([O:13][C:14]1[CH2:19][CH2:18][CH2:17][CH2:16][CH:15]=1)(=[O:12])[CH3:11]

参加物

5

反応物 3

HCID 7967CyclohexanoneHCID 12146Cyclohexyl acetateHCID 178418361HCID 178418361、化合物

生成物 1

HCID 74019Cyclohexene-1-yl acetate

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

Acetic acid in an amount of 15.1 g. was reacted with 6.1 g. cyclohexanone over the catalyst (0.5 g.) described in Example 1. The reaction started at room temperature (25°C.) in the presence of hydrogen and was stopped after 95 minutes, the temperature reaching a high of 84°C. by application of heat. Cyclohexyl acetate was identified as a reaction product by VPC analysis. This reaction in the presence of Amberlyst-15 resin gives a small amount of 1-acetoxycyclohexene; with conventional platinum-on-alumina catalyst it gives cyclohexanol; and with a loose physical mixture of Amberlyst-15 resin and the conventional platinum-on-alumina, the product is cyclohexanol. By "loose" physical mixture is meant a slurry of the type described in Example 2.

後処理

  1. customwas reacted with 6.1 g
  2. customstarted at room temperature
  3. custom(25°C.)
  4. customhigh of 84°C.
  5. temperatureof heat
  6. customThis reaction in the presence of Amberlyst-15 resin

出典と根拠

ORDレコード
ord-b64d2b1d2ae242f08de1f8ccc44a119f
出典データセット
uspto-grants-1976_05
特許番号
US03954883

関連ノート

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