Cyclohexanesulfenyl chloride → HCID 11332618、化合物

反応式

C1(SCl)C=CC=CC=1.[CH2:9]([S:19][Cl:20])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]CCC.ClC(SCl)=CCl.C1C2C(=CC=CC=2)C=CC=1SCl.C1(SCl)CCCCC1>>[C:10]1([CH2:9][S:19][Cl:20])[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1

参加物

反応物 5

HCID 87312Cyclohexanesulfenyl chloride

HCID 11008040Benzenesulfenyl chloride

HCID 124820622-Naphthalenesulfenyl chloride

HCID 21983338HCID 21983338、化合物

HCID 54122024HCID 54122024、化合物

生成物 1

HCID 11332618HCID 11332618、化合物

実験手順

Similarly, repeating the above procedure but replacing the benzenesulfenyl chloride as used therein with an equal molar proportion of each of decanesulfenyl chloride (prepared by chlorination of decanedisulfide according to the method of Douglass, supra.), 1,2-dichlorovinylsulfenyl chloride, 2-naphthalenesulfenyl chloride, cyclohexanesulfenyl chloride (prepared by chlorination of cyclohexanedisulfide, according to the method of Douglass, supra.) and α-toluenesulfenyl chloride, respectively, there is obtained: